(dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran

Base Information

• Chemical Name: (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran
• CAS No.: 877676-53-4
• Molecular Formula: C₄H₈O*C₃₆H₃₀P₂PdS₂
• Molecular Weight: 767.241
• Mol file: 877676-53-4.mol

Synonyms:

Chemical Property of (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran

There total 1 articles about (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(phenyl)(bis-triphenylphosphine)palladium(II) chloride + diphenylphosphinodithioic acid (1015-38-9) → (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II) (877676-52-3) + (dithiodiphenylphosphinate)(phenyl)(triphenylphosphine)palladium(II)*tetrahydrofuran (877676-53-4)

Guidance literature:

With Na₂CO₃; In tetrahydrofuran; methanol; (under Ar, Schlenk); diphenyldithiophosphinic acid dissolved in MeOH-THF, Na2CO3 added, stirred for 1 h, evapd. to dryness, placed under high vac., Na-salt dissolved in THF, added dropwise to Pd(C6H5)Cl(P(C6H5)3)2, stirred for 36 h; filtered, evapd. to dryness, crystd. from THF-pentane and benzene-pentane;

DOI:10.1016/j.ica.2005.10.006

upstream raw materials:

diphenylphosphinodithioic acid