tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4)

Base Information

• Chemical Name: tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4)
• CAS No.: 116323-73-0
• Molecular Formula: BF₄*C₄₉H₆₁O₃P₄PtW
• Molecular Weight: 1287.65
• Mol file: 116323-73-0.mol

Synonyms:

Chemical Property of tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4)

There total 1 articles about tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

trans-PtH(PEt3)2(acetone)(BF4) (84623-75-6) + mer-bis(diphenylphosphino)ethane(carbonyl)3tungsten(CC(H)Ph) (88035-90-9) → tungsten(μ-η1,η4-phenylethylidene)(bis(diphenylphosphino)ethane)(tricarbonyl)bis(triethylphosphine)platinum(II)(BF4) (116323-73-0)

Guidance literature:

In acetone; a soln. of Pt complex is filtered into a stirred soln. of W complex in acetone, color change from deep green to bright orange after 3 min, stirring at 25°C for 1 h (N2); concn., washing twice with diethyl ether, drying in vacuo, crystn. at -15°C from CH2Cl2/hexane, elem. anal.;

upstream raw materials:

trans-PtH(PEt₃)2(acetone)(BF₄)

mer-bis(diphenylphosphino)ethane(carbonyl)3tungsten(CC(H)Ph)