Mo(HS)2(C₆H₄(P(C₆H₅)CH₂CH₂P(C₆H₅)2)2)

Base Information

• Chemical Name: Mo(HS)2(C₆H₄(P(C₆H₅)CH₂CH₂P(C₆H₅)2)2)
• CAS No.: 1122081-15-5
• Molecular Formula: C₄₆H₄₄MoP₄S₂
• Molecular Weight: 880.822
• Mol file: 1122081-15-5.mol

Synonyms:

Chemical Property of Mo(HS)2(C₆H₄(P(C₆H₅)CH₂CH₂P(C₆H₅)2)2)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Mo(HS)2(C₆H₄(P(C₆H₅)CH₂CH₂P(C₆H₅)2)2)

There total 2 articles about Mo(HS)2(C₆H₄(P(C₆H₅)CH₂CH₂P(C₆H₅)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

Mo(dppe)(o-C6H4(PPhCH2CH2PPh2)2) + hydrogen sulfide (7783-06-4) → Mo(HS)2(C6H4(P(C6H5)CH2CH2P(C6H5)2)2) (1122081-15-5)

Guidance literature:

In toluene; (N2); through suspn. of molibdenium complex in toluene, H2S was bubbled for 15 min, stirred for 2 h under H2S atm.; filtered off, washed with toluene, Et2O, dried in vac., elem. anal.;

DOI:10.1039/b902386k

Reference yield: 47.0%

[Mo(η2-MeC2COOMe)(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)]*0.5(toluene) + hydrogen sulfide (7783-06-4) → [Mo(SH)2(κ4-meso-o-C6H4(PPhCH2CH2PPh2)2)] (1122081-15-5)

Guidance literature:

In tetrahydrofuran; byproducts: CH3CH(SH)CH2CO2CH3; (N2); H2S bubbled for 10 min at 0°C through a soln. of Mo complex, stirred at room temp. for 24 h; filtered off, washed (ether), dried (vac.);

DOI:10.1021/om800615a

Reference yield: 76.0%

chlorodicarbonyl(p-toluidine)iridium (14243-22-2,59952-74-8) + Mo(HS)2(C6H4(P(C6H5)CH2CH2P(C6H5)2)2) (1122081-15-5) → (CO)4Ir2MoS2(C6H4(P(C6H5)CH2CH2P(C6H5)2)2)

Guidance literature:

With (C₂H₅)3N; In tetrahydrofuran; dichloromethane; (N2); cold (-78°C) soln. of Et3N and iridium complex in THF was added to soln. of molibdenium complex in CH2Cl2 at -78°C, warmed to room temp. with stirring; filtered, washed with CH2Cl2, dried in vac., elem. anal.;

DOI:10.1039/b902386k

upstream raw materials:

hydrogen sulfide