trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}

Base Information

Chemical Name:trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}
CAS No.:130172-19-9
Molecular Formula:C₁₂H₃₃FeN₂P₄*C₂₄H₂₀B
Molecular Weight:704.383
Hs Code.:

trans-{iron(II)hydrido dinitrogen(Me<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>PMe<sub>2</sub>)2}{BPh<sub>4</sub>}

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Chemical Property of trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}

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Technology Process of trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}

There total 4 articles about trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 16940-66-2
sodium tetrahydroborate

: 60966-88-3,27316-95-6
Fe(1,2-bis(dimethylphosphino)ethane)2Cl₂

: 143-66-8
sodium tetraphenyl borate

: 130172-19-9
trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}

Guidance literature:: With N₂; In ethanol; byproducts: NaCl; treating a slurry of (FeCl2(Me2PC2H4PMe2)2) (2.43 mmol) in ethanol under N2 with NaBH4 in ethanol (2.5 mmol); stirring for 15 min under N2 when color has changed to red-orange; addn. of NaBPh4 (2.6 mmol) in ethanol;; pptn.; stirring for 1 h, filtering; washing with ethanol to remove NaCl, then with ether; drying in vac.; recrystn. from THF or acetone under N2; elem. anal.;
DOI:10.1039/DT9930003041

Reference yield: 70.0%

: 50495-19-7,25145-64-6,41700-58-7
[Mo(N₂)2(1,2-bis(diphenylphosphino)ethane)2]

: 130172-14-4
trans-bis{1,2-bis(dimethylphosphino)ethane}dihydrogenhydridoiron(II) tetraphenylborate

: 32109-09-4
[MoH₄(1,2-bis(diphenylphosphino)ethane)2]

: 130172-19-9
trans-{iron(II)hydrido dinitrogen(Me₂PCH₂CH₂PMe₂)2}{BPh₄}

Guidance literature:: In tetrahydrofuran; stirring (FeH(H2)(Me2PC2H4PMe2)2)BPh4 (0.42 mmol) and (Mo(N2)2(Ph2PC2H4PPh2)2) (0.16 mmol) in THF under Ar at room temp. (react. is monitored by IR-spectroscopy);; removal of solvent in vac. after 18 h; extg. residue with toluene; filtering, concg.; pptn. of (MoH4(Ph2PC2H4PPh2)2) on addn. of MeOH (IR, NMR); recrystn. of residue insol. in toluene from acetone yields (FeH(N2)(Me2PC2H4PMe2)2)BPh4;;
DOI:10.1039/DT9930003041