(10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

Base Information

Chemical Name:(10-methoxy-5,10,15-tritolyl-isocorrolato)Ni
CAS No.:1231259-69-0
Molecular Formula:C₄₁H₃₂N₄NiO
Molecular Weight:655.421
Hs Code.:

Synonyms:

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Chemical Property of (10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

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Technology Process of (10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

There total 2 articles about (10-methoxy-5,10,15-tritolyl-isocorrolato)Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 5-methoxy-5,10,15-isocorrole

: 10-methoxy-5,10,15-isocorrole

: 373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6
nickel diacetate

: 1231259-70-3
(5-methoxy-5,10,15-tritolyl-isocorrolato)Ni

: 1231259-69-0
(10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

Guidance literature:: In N,N-dimethyl-formamide; dissolving of mixt. of 5- and 10-methoxy-5,10,15-tritolyl-isocorrole in DMF, addn. of excess Ni(OAc)2, stirring and reflux for 3 h; monitoring by UV-vis and TLC; cooling, pptn. with H2O, filtration on paper, dissolving in CH2Cl2, drying over Na2SO4, chromy. (silica gel, CH2Cl2), PLC (silica gel, CH2Cl2- hexane 2:1), crystn. from CH2Cl2/CH3OH; elem. anal.;
DOI:10.1021/ic100730j

Reference yield:

: 10-methoxy-5,10,15-isocorrole

: 373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6
nickel diacetate

: 1231259-69-0
(10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

Guidance literature:: In N,N-dimethyl-formamide; dissolving of mixt. of 10-methoxy-5,10,15-tritolyl-isocorrole in DMF, addn. of excess Ni(OAc)2, stirring and reflux for 3 h;
DOI:10.1021/ic100730j

Reference yield:

: 1231259-69-0
(10-methoxy-5,10,15-tritolyl-isocorrolato)Ni

: 1231259-71-4
(5,10,15-tritolyl-isocorrolato)Ni

Guidance literature:: With tetra-n-butylammonium perchlorate; In dichloromethane; Electrochem. Process; (N2); reduction of (10-methoxy-5,10,15-tritolyl-isocorrolato)Ni in CH2Cl2, 0.1 M TBAP in thin-layer cell at potetial of -1.20 V; reoxidation at 0.20 V; monitoring by UV-vis;
DOI:10.1021/ic100730j