C₄₁H₅₆O₆Si

Base Information

• Chemical Name: C₄₁H₅₆O₆Si
• CAS No.: 1334596-42-7
• Molecular Formula: C₄₁H₅₆O₆Si
• Molecular Weight: 672.978
• Mol file: 1334596-42-7.mol

Synonyms:

Chemical Property of C₄₁H₅₆O₆Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₄₁H₅₆O₆Si

There total 7 articles about C₄₁H₅₆O₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-(tert-butyl-dimethyl-silanyloxy)-3,5-dihydroxy-7-(4-methoxy-benzyloxy)-8,8-dimethyl-nonanoic acid methyl ester (935248-47-8) → C41H56O6Si (1334596-42-7)

Guidance literature:

Multi-step reaction with 7 steps

1: pyridinium p-toluenesulfonate / N,N-dimethyl-formamide / 20 °C / Inert atmosphere

2: lithium aluminium tetrahydride / tetrahydrofuran / Inert atmosphere

3: triethylamine tris(hydrogen fluoride) / tetrahydrofuran / Inert atmosphere

4: N,N-dimethyl-formamide / Inert atmosphere

5: Dess-Martin periodane / Inert atmosphere

6: indium / N,N-dimethyl-formamide / Inert atmosphere

7: Dess-Martin periodane / Inert atmosphere

With indium; lithium aluminium tetrahydride; pyridinium p-toluenesulfonate; Dess-Martin periodane; triethylamine tris(hydrogen fluoride); In tetrahydrofuran; N,N-dimethyl-formamide; 5: Dess-Martin oxidation / 7: Dess-Martin oxidation;

DOI:10.1002/chem.201002932

Reference yield:

(3S,5R,7S)-5,7-di-O-isopropylidene-3-(4-methoxybenzyloxy)-9-tert-butyldiphenylsilyloxy-2,2-dimethylnonan-1-ol (1334596-23-4) → C41H56O6Si (1334596-42-7)

Guidance literature:

Multi-step reaction with 3 steps

1: Dess-Martin periodane / Inert atmosphere

2: indium / N,N-dimethyl-formamide / Inert atmosphere

3: Dess-Martin periodane / Inert atmosphere

With indium; Dess-Martin periodane; In N,N-dimethyl-formamide; 1: Dess-Martin oxidation / 3: Dess-Martin oxidation;

DOI:10.1002/chem.201002932

Reference yield:

C28H50O6Si (1334596-22-3) → C41H56O6Si (1334596-42-7)

Guidance literature:

Multi-step reaction with 5 steps

1: triethylamine tris(hydrogen fluoride) / tetrahydrofuran / Inert atmosphere

2: N,N-dimethyl-formamide / Inert atmosphere

3: Dess-Martin periodane / Inert atmosphere

4: indium / N,N-dimethyl-formamide / Inert atmosphere

5: Dess-Martin periodane / Inert atmosphere

With indium; Dess-Martin periodane; triethylamine tris(hydrogen fluoride); In tetrahydrofuran; N,N-dimethyl-formamide; 3: Dess-Martin oxidation / 5: Dess-Martin oxidation;

DOI:10.1002/chem.201002932

upstream raw materials:

9-(tert-butyl-dimethyl-silanyloxy)-3,5-dihydroxy-7-(4-methoxy-benzyloxy)-8,8-dimethyl-nonanoic acid methyl ester

(3S,5R,7S)-5,7-di-O-isopropylidene-3-(4-methoxybenzyloxy)-9-tert-butyldiphenylsilyloxy-2,2-dimethylnonan-1-ol

C₂₉H₅₀O₇Si

C₂₈H₅₀O₆Si