Os(CO)3H₂(P(C₆H₅)3)

Base Information

Chemical Name:Os(CO)3H₂(P(C₆H₅)3)
CAS No.:99782-58-8
Molecular Formula:C₂₁H₁₇O₃OsP
Molecular Weight:538.538
Hs Code.:

Os(CO)3H<sub>2</sub>(P(C<sub>6</sub>H<sub>5</sub>)3)

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Os(CO)3H₂(P(C₆H₅)3)

Chemical Property:

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Technology Process of Os(CO)3H₂(P(C₆H₅)3)

There total 3 articles about Os(CO)3H₂(P(C₆H₅)3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 25685-05-6
octacarbonyldihydridodiosmium

: 33635-53-9,21192-24-5
Os(CO)4(triphenylphosphine)

: 18972-43-5,99782-58-8
Os(CO)3H₂(P(C₆H₅)3)

: 62976-01-6
Os₂(CO)7H₂(P(C₆H₅)3)

: 62793-33-3
hexacarbonyldihydridobis(triphenylphosphine)diosmium

Guidance literature:: With triphenylphosphine; In benzene; N2-atmosphere; refluxing (2 h); solvent removal (reduced pressure), washing (hexane), recrystn. (CH2Cl2/hexane); elem. anal.;
DOI:10.1039/DT9770000089

Reference yield:

: methyl(triphenylphosphine)gold(I)

: 22372-70-9
tetracarbonyldihydroosmium

: 99782-58-8
H₂Os(CO)3P(C₆H₅)3

: 99747-68-9
((C₆H₅)3PAu)2Os(CO)4

Guidance literature:: With 2,2'-azobis(isobutyronitrile); triphenylphosphine; In benzene-d6; byproducts: methane; an NMR tube was charged with Ph3PAuMe, PPh3 and AIBN, C6D6 and H2Os(CO)4 were added under vac., sealed tube was heated at 35°C for 2 h; H2Os(CO)3PPh3 to (Ph3PAu)2Os(CO)4 ratio 62:38; (1)H NMR spectral data;
DOI:10.1021/ja00265a018

Reference yield:

: 22372-70-9
tetracarbonyldihydroosmium

: 18974-23-7,25702-68-5
dicarbonyldihydridobis(triphenylphosphine)osmium

: 99782-58-8
H₂Os(CO)3P(C₆H₅)3

Guidance literature:: With 2,2'-azobis(isobutyronitrile); triphenylphosphine; In benzene; H2Os(CO)4 was transferred in vacuo to a vacuum-line reaction bulb containing PPh3, AIBN and benzene, soln. was degassed, kept at 35°C; reaction mixt. was sampled by quenching the soln. at 0°C and removing of aliquot by syringe under a heavy flow of N2 or Ar; product was identified by its IR spectrum; Kinetics;
DOI:10.1021/ja00265a018