trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

Base Information

Chemical Name:trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone
CAS No.:124354-44-5
Molecular Formula:C₃H₆O*C₄₂H₃₇Br₂N₂P₂ReS
Molecular Weight:1067.88
Hs Code.:

Synonyms:

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Chemical Property of trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

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Technology Process of trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

There total 3 articles about trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: [ReOBr₂(C₆H₇N₂S)(P(C₆H₅)3)]

: 603-35-0
triphenylphosphine

: 124354-44-5
trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

Guidance literature:: In acetone; reflux (ca 6 h);
DOI:10.1016/S0277-5387(96)00505-0

Reference yield: 56.0%

: 18703-08-7,80227-23-2
trans-dibromo(ethoxo)oxobis(triphenylphosphine)rhenium(V)

: 22325-27-5,131321-42-1
4,6-dimethyl-2-meraptopyrimidine

: 124354-44-5
trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

Guidance literature:: In acetone; reflux (6 h); filtration, washing (acetone), drying; elem. anal.;
DOI:10.1016/S0277-5387(96)00505-0

Reference yield:

: trans-oxotribromobis(triphenylphosphine)rhenium(V)

: 22325-27-5
4,6-dimethyl-pyrimidine-2-thione

: 107708-08-7
4,6-dimethyl-2-sulfanylidene-2,3-dihydropyrimidin-1-ium bromide

: 124354-44-5
trans-rhenium(III)(Br)2(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)2*acetone

: 123995-85-7
trans-rhenium(V)-oxo-Br₂(4,6-dimethylpyrimidine-2-thiolate)(triphenylphosphine)

Guidance literature:: With ligroine; In acetone; Addn. of (pymSH) to suspn. of ReOBr3(PPh3)2 (acetone) under stirring, refluxing of mixt. (2 h), standing of orange soln. and mixt. of microcrystals overnight,; filtn., removal of C6H9BrN2S through washing with MeOH yields Re(V)-oxo-complex. Slow concn. at room temp., washing (acetone, ether), drying (vac.), yields Re(III) compd., elem. anal.;
DOI:10.1007/BF01185388