Technology Process of C14H8(C6H5)2Si(CH3)2
There total 4 articles about C14H8(C6H5)2Si(CH3)2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate;
In
water; toluene;
for 16h;
Inert atmosphere;
Reflux;
DOI:10.1021/om2000597
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium tert-butylate / Inert atmosphere
1.2: Inert atmosphere
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 °C / Inert atmosphere
2.3: -78 - 20 °C / Inert atmosphere
3.1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate / water; toluene / 16 h / Inert atmosphere; Reflux
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; n-butyllithium; potassium tert-butylate; palladium diacetate;
In
diethyl ether; hexane; water; toluene;
1.2: Wittig reaction / 3.1: Suzuki coupling;
DOI:10.1021/om2000597
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium tert-butylate / Inert atmosphere
1.2: Inert atmosphere
2.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C / Inert atmosphere
2.2: 2 h / -78 °C / Inert atmosphere
2.3: -78 - 20 °C / Inert atmosphere
3.1: dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; palladium diacetate / water; toluene / 16 h / Inert atmosphere; Reflux
With
dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; n-butyllithium; potassium tert-butylate; palladium diacetate;
In
diethyl ether; hexane; water; toluene;
1.2: Wittig reaction / 3.1: Suzuki coupling;
DOI:10.1021/om2000597
