[Pt(2,6-Me₂C₆H₃N=CHCH=N-2,6-Me₂C₆H₃)Me₂]

Base Information

• Chemical Name: [Pt(2,6-Me₂C₆H₃N=CHCH=N-2,6-Me₂C₆H₃)Me₂]
• CAS No.: 200574-35-2
• Molecular Formula: C₂₀H₂₆N₂Pt
• Molecular Weight: 489.52
• Mol file: 200574-35-2.mol

Synonyms:

Chemical Property of [Pt(2,6-Me₂C₆H₃N=CHCH=N-2,6-Me₂C₆H₃)Me₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(2,6-Me₂C₆H₃N=CHCH=N-2,6-Me₂C₆H₃)Me₂]

There total 2 articles about [Pt(2,6-Me₂C₆H₃N=CHCH=N-2,6-Me₂C₆H₃)Me₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

glyoxalbis(2,6-dimethylphenylimine) + [PtMe2(SMe2)]2 → [Pt(2,6-Me2C6H3N=CHCH=N-2,6-Me2C6H3)Me2] (200574-35-2)

Guidance literature:

In toluene; under Ar atm. (Me2Pt(SMe2))2 was dissolved in toluene, α-diimine was added and stirred overnight at r.t.; solvent was reduced, p.e. was added, product was filtered; elem. anal.;

DOI:10.1002/1522-2675(20011017)84:10<3247::AID-HLCA3247>3.0.CO;2-W

Reference yield: 54.0%

bis[dimethyl(μ-dimethylsulfide)platinum(II)] + glyoxalbis(2,6-dimethylphenylimine) → [Pt(2,6-Me2C6H3N=CHCH=N-2,6-Me2C6H3)Me2] (200574-35-2)

Guidance literature:

In toluene; (under N2, Schlenk); ligand added to soln. of Pt-complex in toluene, stirred for 3 h; filtered, solvent removed under vac., residue dissolved in ether, filtered, pentane added, stored at -30°C for 15 h; elem. anal.;

DOI:10.1016/j.jorganchem.2007.02.040

Reference yield: 91.0%

[Pt(2,6-Me2C6H3N=CHCH=N-2,6-Me2C6H3)Me2] (200574-35-2) + 1,1,1,2,2,3,3-heptafluoro-3-iodo-propane (754-34-7) → [1,2-bis(2,6-dimethylphenylimino)ethane](heptafluoropropyl)methylplatinum(II) (676364-14-0)

Guidance literature:

In hexane; under N2 atm. to son. Pt complex in hexane C3F7I was added and heated atreflux for 18 h; react. mixt. was cooled, product was filtered and washed with hexane; elem. anal.;

DOI:10.1139/v03-117

Downstream raw materials:

(2,6-Me₂PhDAB(H))PtI₂Me₂

Pt(CH₃)2(((CH₃)2C₆H₃NCH)2)^(1-)

(2,6-Me₂PhDAB(H))PtCl₂Me₂

[1,2-bis(2,6-dimethylphenylimino)ethane](heptafluoropropyl)methylplatinum(II)