dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato^(1-)]bis(triphenylphosphine)ruthenium(II)*CH₂Cl₂*CH₃OH

Base Information

• Chemical Name: dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato^(1-)]bis(triphenylphosphine)ruthenium(II)*CH₂Cl₂*CH₃OH
• CAS No.: 90479-86-0
• Molecular Formula: CH₂Cl₂*CH₄O*C₇₀H₆₀O₁₄P₂Ru
• Molecular Weight: 1405.23
• Mol file: 90479-86-0.mol

Synonyms:

Chemical Property of dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato^(1-)]bis(triphenylphosphine)ruthenium(II)*CH₂Cl₂*CH₃OH

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato^(1-)]bis(triphenylphosphine)ruthenium(II)*CH₂Cl₂*CH₃OH

There total 1 articles about dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato^(1-)]bis(triphenylphosphine)ruthenium(II)*CH₂Cl₂*CH₃OH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7) + 1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethane (79906-09-5) → dicarbonylbis[1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethanato(1-)]bis(triphenylphosphine)ruthenium(II)*CH2Cl2*CH3OH (90479-86-0)

Guidance literature:

In 2-methoxy-ethanol; Ru-complex was suspended in 2-methoxyethanol and ligand was added, mixt. was refluxed for 30 min; solvent was removed on a rotary evaporator, dissolved in CH2Cl2-MeOH, was allowed to stand overnight, crystals were collected, washed with MeOH, dried in vac.; elem. anal.;

DOI:10.1039/DT9840000739

upstream raw materials:

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

1-(o-carboxymethoxyphenoxy)-2-(o-hydroxyphenoxy)ethane