cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

Base Information

Chemical Name:cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]
CAS No.:200009-40-1
Molecular Formula:C₂₉H₃₀P₂PdS₂
Molecular Weight:611.057
Hs Code.:

Synonyms:

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Chemical Property of cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

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Technology Process of cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

There total 1 articles about cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 23851-06-1,23851-16-3
disodium 1,2-ethanedithiolate

: palladium dichloride

: 200009-40-1
cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

Guidance literature:: In ethanol; acetonitrile; under N2; mixt. of PdCl2 and ligand in MeCN was stirred for 1 h at room temp., Na-salt in EtOH was added, stirred for 2 h; filtered, filtrate was kept at 4°C for 2 d, filtered, washed withwater, EtOH, and Et2O, dried in vac.; elem. anal.;
DOI:10.1039/a908788e

Reference yield: 84.0%

: 59420-05-2
bis(cyclooctadiene)rhodium(I) perchlorate

: 200009-40-1
cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

: 200009-32-1
[(1,3-bis(diphenylphosphino)propane)Pd(μ-ethane-1,2-dithiolate)Rh(1,5-cyclooctadiene)]ClO4

Guidance literature:: In dichloromethane; byproducts: COD; N2-atmosphere; stirring stoich. amts. at room temp. for 30 min; concn., crystn. on addn. or vapor diffusion of hexane; elem. anal.;
DOI:10.1021/ic970557o

Reference yield: 30.0%

: 200009-40-1
cis-[Pd(ethane-1,2-dithiolate)(1,3-bis(diphenylphosphino)propane)]

: 80937-33-3
oxygen

: [Pd₂(O₂SCH₂CH₂SO₂)P(C₆H₅)2CH₂CH₂CH₂P(C₆H₅)2(SCH₂CH₂S)]*0.5H₂O

Guidance literature:: With CH₃ONa; In N,N-dimethyl-formamide; to soln. of Pd-complex in DMF solid MeONa was added with stirring, O2 was bubbled into mixt. at ambient temp. and at 90°C for 8 h, cooledto room temp.; filtered, filtrate cooled at 4°C for 1 wk; elem. anal.;
DOI:10.1039/a908788e