(+)-gamma-Cadinene

Base Information

• Chemical Name: (+)-gamma-Cadinene
• CAS No.: 483-74-9
• Molecular Formula: C₁₅H₂₄
• Molecular Weight: 204.356
• UNII: 195FU8L66T
• DSSTox Substance ID: DTXSID80197482
• Nikkaji Number: J12.840F
• Wikidata: Q27132468
• Metabolomics Workbench ID: 48104
• Mol file: 483-74-9.mol

Synonyms:gamma-cadinene;gamma-cadinene, (+)-gamma(1)-isomer;gamma-cadinene, (+)-isomer;gamma-cadinene, (-)-isomer

Chemical Property of (+)-gamma-Cadinene

Chemical Property:

• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 204.187800766
• Heavy Atom Count: 15
• Complexity: 282

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC1=CC2C(CC1)C(=C)CCC2C(C)C
• Isomeric SMILES: CC1=C[C@@H]2[C@@H](CC1)C(=C)CC[C@H]2C(C)C

Technology Process of (+)-gamma-Cadinene

There total 5 articles about (+)-gamma-Cadinene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+)-α-cadinol (481-34-5,5937-11-1,19435-97-3,19912-62-0,39864-11-4,43060-37-3,58560-29-5,58580-31-7,65700-78-9,71300-63-5,81967-90-0,95342-27-1,106035-59-0,133645-25-7) → (-)-γ-cadinene (483-74-9,1460-97-5,6980-46-7,10208-81-8,24268-39-1,28080-00-4,30021-74-0,38357-83-4,39029-41-9,41610-66-6,68000-46-4)

Guidance literature:

With trichlorophosphate; In pyridine; benzene; for 2h; Ambient temperature;

DOI:10.1016/S0040-4020(01)86837-X

Reference yield:

vetidiol (113888-82-7) → (-)-γ-cadinene (483-74-9,1460-97-5,6980-46-7,10208-81-8,24268-39-1,28080-00-4,30021-74-0,38357-83-4,39029-41-9,41610-66-6,68000-46-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 125 mg / PBA / CHCl₃ / 24 h / 0 °C

2: pyridine

3: LAH / 20 h / Heating

4: POCl₃ / pyridine; benzene / 2 h / Ambient temperature

With lithium aluminium tetrahydride; trichlorophosphate; In pyridine; chloroform; benzene;

DOI:10.1016/S0040-4020(01)86837-X

Reference yield:

C15H24O3 (113888-83-8) → (-)-γ-cadinene (483-74-9,1460-97-5,6980-46-7,10208-81-8,24268-39-1,28080-00-4,30021-74-0,38357-83-4,39029-41-9,41610-66-6,68000-46-4)

Guidance literature:

Multi-step reaction with 3 steps

1: pyridine

2: LAH / 20 h / Heating

3: POCl₃ / pyridine; benzene / 2 h / Ambient temperature

With lithium aluminium tetrahydride; trichlorophosphate; In pyridine; benzene;

DOI:10.1016/S0040-4020(01)86837-X

upstream raw materials:

(+)-α-cadinol

vetidiol

C₁₅H₂₄O₃

C₂₉H₃₆O₇S₂