tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside
CAS No.:152508-15-1
Molecular Formula:C₄₄H₆₆O₂₁Si
Molecular Weight:959.081
Hs Code.:

tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

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Chemical Property of tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

Chemical Property:

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Technology Process of tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

There total 3 articles about tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: acetyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-2,4,6-tri-O-acetyl-α/β-D-glucopyranoside

: 152508-15-1
tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 76 percent / hydrazinium acetate / dimethylformamide / 60 °C

2: 87 percent / 1,8-diazabicyclo<5.4.0>undecene / CH₂Cl₂ / 4 h

3: 1.) molecular sieves / 2.) trimethylsilyl trifluoromethanesulfonate / 1.) CH₂Cl₂, 15 min, 2.) CH₂Cl₂, 40 min

With molecular sieve; hydrazinium monoacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; N,N-dimethyl-formamide;

Reference yield:

: O-2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-acetyl-α/β-D-glucopyranose

: 152508-15-1
tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / 1,8-diazabicyclo<5.4.0>undecene / CH₂Cl₂ / 4 h

2: 1.) molecular sieves / 2.) trimethylsilyl trifluoromethanesulfonate / 1.) CH₂Cl₂, 15 min, 2.) CH₂Cl₂, 40 min

With molecular sieve; 1,8-diazabicyclo[5.4.0]undec-7-ene; trimethylsilyl trifluoromethanesulfonate; In dichloromethane;

Reference yield:

: 142657-03-2
tert-Butyldimethylsilyl 3-O-Benzyl-6-deoxy-β-D-glucopyranoside

: 152508-12-8
O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-α-D-glucopyranosyl) trichloroacetimidate

: 152508-15-1
tert-butyldimethylsilyl O-(2,4,6-tri-O-acetyl-3-O-methyl-β-D-glucopyranosyl)-(1->3)-(2,4,6-tri-O-acetyl-β-D-glucopyranosyl)-(1->4)-3-O-benzyl-6-deoxy-β-D-glucopyranoside

Guidance literature:: With molecular sieve; trimethylsilyl trifluoromethanesulfonate; Yield given. Multistep reaction; 1.) CH₂Cl₂, 15 min, 2.) CH₂Cl₂, 40 min;