CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

Base Information

Chemical Name:CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2
CAS No.:112680-79-2
Molecular Formula:C₁₂CrMoO₁₂SW*2C₃₆H₃₀NP₂
Molecular Weight:1777.15
Hs Code.:

CrMoW(CO)12S<sup>(2-)</sup>*2(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>={CrMoW(CO)12S}{(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3}2

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Chemical Property of CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

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Technology Process of CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

There total 1 articles about CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.6%

: sodium hydrogen sulfide

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tungsten hexacarbonyl

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pentacarbonyl(tetrahydrofuran)molybdenum⁽⁰⁾

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pentacarbonyl(tetrahydrofuran)chromium⁽⁰⁾

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bis(triphenylphosphine)iminium chloride

: 112680-79-2
CrMoW(CO)12S^(2-)*2(C₆H₅)3PNP(C₆H₅)3⁽¹⁺⁾={CrMoW(CO)12S}{(C₆H₅)3PNP(C₆H₅)3}2

Guidance literature:: With NaH; In ethanol; NaSH, {PPN}Cl stirred in EtOH for 3h, solvent removal, addn. of W(CO)6 in THF, reflux. for 1h ->{W(CO)5SH}PPN; cooled in a dry ice/acetone slush, filtered, addn. of Cr(CO)5THF, addn. of NaH, then Mo(CO)5THF; addn. of{PPN}Cl,EtOH, stirred for 1h; solvent removal, residue was dissolved in acetone and precipitated with diethyl ether; elemental analysis;