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IrH2(CO)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CO)(C6H5P((CH2)3P(C6H11)2)2)}{BF4}

Base Information
  • Chemical Name:IrH2(CO)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CO)(C6H5P((CH2)3P(C6H11)2)2)}{BF4}
  • CAS No.:103746-23-2
  • Molecular Formula:BF4*C37H63IrOP3
  • Molecular Weight:895.853
  • Hs Code.:
IrH<sub>2</sub>(CO)(C<sub>6</sub>H<sub>5</sub>P(CH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)2)<sup>(1+)</sup>*BF<sub>4</sub><sup>(1-)</sup>={IrH<sub>2</sub>(CO)(C<sub>6</sub>H<sub>5</sub>P((CH<sub>2</sub>)3P(C<sub>6</sub>H<sub>11</sub>)2)2)}{BF<sub>4</sub>}

Synonyms:

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Chemical Property of IrH2(CO)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CO)(C6H5P((CH2)3P(C6H11)2)2)}{BF4}
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Technology Process of IrH2(CO)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CO)(C6H5P((CH2)3P(C6H11)2)2)}{BF4}

There total 3 articles about IrH2(CO)(C6H5P(CH2CH2CH2P(C6H11)2)2)(1+)*BF4(1-)={IrH2(CO)(C6H5P((CH2)3P(C6H11)2)2)}{BF4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With carbon monoxide; In tetrahydrofuran; byproducts: TlCl; nitrogen atmosphere; a slow stream of CO bubbles is introduced into the soln. of the Ir complex and TlBF4*6H2O (3 h); soln. purged with N2 (15 min), TlCl removed by filtration; removal of the solvent (red. pressure); extn. (acetone), solvent removed (red. pressure), product washed with water, recrystd. (acetone/ether); elem. anal.;
Guidance literature:
With CO; In tetrahydrofuran; introduction of CO into THF soln. containing equivalent amts. of Ir-complex and TlBF4 over a period of 4 h; extraction with acetone; elem. anal.;
DOI:10.1016/S0020-1693(00)86441-5
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