{(5,10,15,20-tetraphenylporphyrinato)manganese(III)}⁽²⁺⁾

Base Information

• Chemical Name: {(5,10,15,20-tetraphenylporphyrinato)manganese(III)}⁽²⁺⁾
• CAS No.: 83042-12-0
• Molecular Formula: C₄₄H₂₈MnN₄
• Molecular Weight: 667.671

Synonyms:

Chemical Property of {(5,10,15,20-tetraphenylporphyrinato)manganese(III)}⁽²⁺⁾

Chemical Property:

Purity/Quality:

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Technology Process of {(5,10,15,20-tetraphenylporphyrinato)manganese(III)}⁽²⁺⁾

There total 2 articles about {(5,10,15,20-tetraphenylporphyrinato)manganese(III)}⁽²⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

manganese(III) 5,10,15,20-tetrakis(phenyl)porphyrin → Mn(IV)TPP (83042-12-0)

Guidance literature:

With phenoxathiinylium hexachloroantimonate; In dichloromethane; under N2, slight excess of phenoxathiinylium hexachloroantimonate addedto CH2Cl2 soln. of Mn-compd., stirred for a few min; filtered under vac., filtrate maintained at -70°C, pptd. by adding dry heptane;

DOI:10.1039/DT9820001231

Reference yield:

manganese(III) 5,10,15,20-tetrakis(phenyl)porphyrin → {(5,10,15,20-tetraphenylporphyrinato)manganese(III)}(2+) (83042-12-0)

Guidance literature:

With bromate; In further solvent(s); under N2, oxidn. in cetyltrimethylammonium chloride micelles at pH 12, ca. 100 fold excess of oxidant; followed by UV-vis spectra;

DOI:10.1039/DT9820001231

Reference yield:

{(5,10,15,20-tetraphenylporphyrinato)manganese(III)}(2+) (83042-12-0) → manganese(III) 5,10,15,20-tetrakis(phenyl)porphyrin

Guidance literature:

In further solvent(s); other Radiation; under N2, soln. of Mn-compd. in aq. cetyltrimethylammonium chloride stood in the dark for a few h, catalysed by red light; followed by UV-vis spectra;

DOI:10.1039/DT9820001231

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