mer-IrCl₃(PMePh₂)3

Base Information

• Chemical Name: mer-IrCl₃(PMePh₂)3
• CAS No.: 15526-77-9
• Molecular Formula: C₃₉H₃₉Cl₃IrP₃
• Molecular Weight: 899.239
• Mol file: 15526-77-9.mol

Synonyms:

Chemical Property of mer-IrCl₃(PMePh₂)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of mer-IrCl₃(PMePh₂)3

There total 2 articles about mer-IrCl₃(PMePh₂)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

iridium(III) chloride trihydrate + diphenyl(methyl)phosphine (1486-28-8) → IrCl3(PPh2Me)3 (23171-48-4,15526-77-9,55222-28-1)

Guidance literature:

With HCl; In ethanol; mixt. of concd. HCl and Ir-compound heated at 78°C for 45 min; cooled to room temp.; addn. of PPh2Me; heated at 80 °C for 6 h;; cooling; filtration; filtrate evapd.; extn. (toluene); concn.; crystn. by cooling to -15°C; elem. anal.;

DOI:10.1039/DT9930003359

Reference yield:

sodium hexachloroiridate + diphenyl(methyl)phosphine (1486-28-8) → mer-IrCl3(PMePh2)3 (15526-77-9,23171-48-4,55222-28-1)

Guidance literature:

With hydrogenchloride; In ethanol; Na2IrCl6 in ethanol was heated under reflux in the presence of concd. HCl for 1 h, soln. was cooled to room temp. and phosphine was added and the mixt. was heated under reflux for 3-5 h; Jenkins J. M., Shaw B. L., J. Chem. Soc., 1965, 6789.; solvent was removed, residue was extd. with boiling benzene, the soln. was pumped to dryness and ppt. was recrystd. from ethyl-methyl ketone;

DOI:10.1016/S0020-1693(00)85216-0

Reference yield: 83.0%

IrCl3(PPh2Me)3 (23171-48-4,15526-77-9,55222-28-1) + (2-mercaptophenyl)diphenylphosphine (119327-17-2) → [IrCl2(2-diphenylphosphinobenzenethiolate)(PMePh2)2] (165602-95-9)

Guidance literature:

With NEt₃; In methanol; N2-atmosphere; refluxing of Ir-complex with 4 equiv. of ligand and NEt3(3 h, pptn.); elem. anal.;

DOI:10.1039/DT9950001957

upstream raw materials:

diphenyl(methyl)phosphine

Downstream raw materials:

[IrCl₂(2-diphenylphosphinobenzenethiolate)(PMePh₂)2]