[dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane

Base Information

• Chemical Name: [dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane
• CAS No.: 216693-28-6
• Molecular Formula: C₄₆H₅₄GeOSi
• Molecular Weight: 723.61
• Mol file: 216693-28-6.mol

Synonyms:

Chemical Property of [dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane

There total 1 articles about [dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

triethylsilane (617-86-7) + SiGe2(C9H11)6 + trans-2-phenylcyclopropanecarbaldehyde (34271-31-3) → 2,2,3,3-tetramesityl-4-phenyloxa-2,3-silagermacyclohept-6-ene (216693-33-3) + [dimesityl(2-cis-4-trans-1-oxa-5-phenylpentadienyl)silyl]dimesitylgermane (216693-28-6)

Guidance literature:

In toluene; Irradiation (UV/VIS); photolyzing SiGe2Mes6 and Et3SiH (350 nm, -70°C, 12 h); cyclopropane compd. addn. (22°C, 2 h); chromy. (30/70 CH2Cl2/hexanes, 5/95 Et2O/hexanes);

DOI:10.1021/ja9812002

upstream raw materials:

triethylsilane

trans-2-phenylcyclopropanecarbaldehyde