Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

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Chemical Name:Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester
CAS No.:187219-54-1
Molecular Formula:C₂₉H₃₇NO₆
Molecular Weight:495.616
Hs Code.:

Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

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Chemical Property of Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

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Technology Process of Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

There total 9 articles about Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 187219-53-0
Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-acetoxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

: 187219-54-1
Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Guidance literature:: With hydrogenchloride; methanol; at 45 ℃; for 18h;
DOI:10.1135/cccc19961647

Reference yield:

: 151051-61-5
15β-hydroxyandrost-5-ene-3β,17β-diyl diacetate

: 187219-54-1
Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 81 percent / Jones reagent / acetone / 0.08 h / Ambient temperature

2: pyridine / 18 h / Ambient temperature

3: diethyl ether; methanol

4: 33 percent / HCl/MeOH / 3 h / 18 °C

5: 71 percent / pyridine / 18 h / Ambient temperature

6: 72 percent / HCl/MeOH / 18 h / 45 °C

With pyridine; hydrogenchloride; methanol; jones reagent; In methanol; diethyl ether; acetone;
DOI:10.1135/cccc19961647

Reference yield:

: 151051-62-6
15-oxoandrost-5-ene-3β,17β-diyl diacetate

: 187219-54-1
Benzoic acid (3S,8R,9S,10R,13S,14S,17S)-17-hydroxy-15-[(E)-methoxycarbonylmethoxyimino]-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine / 18 h / Ambient temperature

2: diethyl ether; methanol

3: 33 percent / HCl/MeOH / 3 h / 18 °C

4: 71 percent / pyridine / 18 h / Ambient temperature

5: 72 percent / HCl/MeOH / 18 h / 45 °C

With pyridine; hydrogenchloride; methanol; In methanol; diethyl ether;
DOI:10.1135/cccc19961647