tricyclo<4.2.1.0^1,6>nonane-9-carboxaldehyde tosylhydrazone

Base Information

• Chemical Name: tricyclo<4.2.1.0^1,6>nonane-9-carboxaldehyde tosylhydrazone
• CAS No.: 80657-68-7
• Molecular Formula: C₁₇H₂₂N₂O₂S
• Molecular Weight: 318.44
• Mol file: 80657-68-7.mol

Synonyms:

Chemical Property of tricyclo<4.2.1.0^1,6>nonane-9-carboxaldehyde tosylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricyclo<4.2.1.0^1,6>nonane-9-carboxaldehyde tosylhydrazone

There total 5 articles about tricyclo<4.2.1.0^1,6>nonane-9-carboxaldehyde tosylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bicyclo<4.2.0>oct-1(6)-ene (10563-11-8) → tricyclo<4.2.1.01,6>nonane-9-carboxaldehyde tosylhydrazone (80625-12-3,80657-68-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 41 percent / cupric sulfate / cyclohexane / 0.25 h / Heating

2: 74 percent / LiAlH₄ / diethyl ether / 1.5 h / Heating

3: CrO₃, pyridine / CH₂Cl₂ / 0.25 h

4: ethanol / Ambient temperature; overnight

With pyridine; chromium(VI) oxide; lithium aluminium tetrahydride; copper(II) sulfate; In diethyl ether; ethanol; dichloromethane; cyclohexane;

DOI:10.1021/jo00344a019

Reference yield:

9-(hydroxymethyl)tricyclo<4.2.1.01,6>nonanes (80625-10-1,80657-67-6) → tricyclo<4.2.1.01,6>nonane-9-carboxaldehyde tosylhydrazone (80625-12-3,80657-68-7)

Guidance literature:

Multi-step reaction with 2 steps

1: CrO₃, pyridine / CH₂Cl₂ / 0.25 h

2: ethanol / Ambient temperature; overnight

With pyridine; chromium(VI) oxide; In ethanol; dichloromethane;

DOI:10.1021/jo00344a019

Reference yield:

9-(carboethoxy)tricyclo<4.2.1.01,6>nonanes (80625-08-7,80625-09-8) → tricyclo<4.2.1.01,6>nonane-9-carboxaldehyde tosylhydrazone (80625-12-3,80657-68-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 74 percent / LiAlH₄ / diethyl ether / 1.5 h / Heating

2: CrO₃, pyridine / CH₂Cl₂ / 0.25 h

3: ethanol / Ambient temperature; overnight

With pyridine; chromium(VI) oxide; lithium aluminium tetrahydride; In diethyl ether; ethanol; dichloromethane;

DOI:10.1021/jo00344a019

upstream raw materials:

Tricyclo[4.2.1.0^1,6]nonane-9-carbaldehyde

toluene-4-sulfonic acid hydrazide

bicyclo<4.2.0>oct-1(6)-ene

9-(hydroxymethyl)tricyclo<4.2.1.0^1,6>nonanes