Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]-

Base Information

Chemical Name:Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]-
CAS No.:106094-31-9
Molecular Formula:C18H34O2Si
Molecular Weight:310.552
Hs Code.:

Synonyms:

Suppliers and Price of Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]-

Chemical Property:

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]-

There total 1 articles about Silane, trimethyl[10-[(tetrahydro-2H-pyran-2-yl)oxy]-1-decynyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50816-20-1
2-(8-bromooctyloxy)tetrahydropyran

: 1066-54-2
trimethylsilylacetylene

: 19754-58-6
2-dec-9-ynyloxy-tetrahydro-pyran

: 106094-31-9
trimethyl-(10-((tetrahydro-2H-pyran-2-yl)oxy)dec-1-yn-1-yl)silane

Guidance literature:: trimethylsilylacetylene; With n-butyllithium; In tetrahydrofuran; cyclohexane; at -60 - 0 ℃; for 0.5h;

2-(8-bromooctyloxy)tetrahydropyran; With N,N,N,N,N,N-hexamethylphosphoric triamide; In tetrahydrofuran; cyclohexane; at -20 - 20 ℃; for 19h;
DOI:10.1016/j.bmc.2013.05.013

Reference yield:

: 106094-31-9
trimethyl-(10-((tetrahydro-2H-pyran-2-yl)oxy)dec-1-yn-1-yl)silane

: 50767-79-8
(9Z,11E)-9,11-tetradecadiene-1-yl acetate

Guidance literature:: Multi-step reaction with 6 steps

1: 79 percent / diisobutylaluminum hydride / diethyl ether / 3.33 h / 25 - 40 °C

2: pyridine, NBS / diethyl ether / 1.25 h / 25 - 30 °C / Irradiation

3: 1.) Br₂, 2.) tetrabutylammonium fluoride trihydrate / 1.) CH₂Cl₂, -78 deg C, 2.) THF, CH₂Cl₂, -20 deg C

4: 85 percent / EtONa, BHA, Pd(PPh₃)4 / toluene; ethanol / 0.75 h / 65 °C

5: pyridinium tosylate, BHA, / ethanol / 3 h / 45 °C

6: pyridine / -10 °C

With pyridine; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 3-tert-Butyl-4-hydroxyanisole; tetrabutyl ammonium fluoride; bromine; sodium ethanolate; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; In diethyl ether; ethanol; toluene;
DOI:10.1021/jo00378a029

Reference yield:

: 106094-31-9
trimethyl-(10-((tetrahydro-2H-pyran-2-yl)oxy)dec-1-yn-1-yl)silane

: 54664-97-0
(9Z,11Z)-9,11-tetradecadienol acetate

Guidance literature:: Multi-step reaction with 6 steps

1: 79 percent / diisobutylaluminum hydride / diethyl ether / 3.33 h / 25 - 40 °C

2: pyridine, NBS / diethyl ether / 1.25 h / 25 - 30 °C / Irradiation

3: 1.) Br₂, 2.) tetrabutylammonium fluoride trihydrate / 1.) CH₂Cl₂, -78 deg C, 2.) THF, CH₂Cl₂, -20 deg C

4: 63 percent / EtONa, BHA, Pd(PPh₃)4 / toluene; ethanol / 0.75 h / 65 °C

5: pyridinium tosylate, BHA, / ethanol / 3 h / 45 °C

6: pyridine / -10 °C

With pyridine; N-Bromosuccinimide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 3-tert-Butyl-4-hydroxyanisole; tetrabutyl ammonium fluoride; bromine; sodium ethanolate; pyridinium p-toluenesulfonate; diisobutylaluminium hydride; In diethyl ether; ethanol; toluene;
DOI:10.1021/jo00378a029