cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

Base Information

Chemical Name:cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane
CAS No.:130256-38-1
Molecular Formula:C₁₈H₂₄O₅
Molecular Weight:320.386
Hs Code.:

Synonyms:

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Chemical Property of cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

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Technology Process of cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

There total 9 articles about cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 50409-13-7
2,5,11-trioxatricyclo[4.3.1.14,8 ] undecan-3-one

: 130256-38-1
cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

Guidance literature:: Multi-step reaction with 8 steps

1: 90 percent / NaBH₄ / ethanol / Ambient temperature

2: 73 percent / t.BuOK / 2-methyl-propan-2-ol / 65 °C

3: 96 percent / (COCl)2, DMSO / CH₂Cl₂ / -60 °C

4: 64 percent / Zn, TiCl₄ / tetrahydrofuran; CH₂Cl₂ / 0 °C

5: 88 percent / BH_3.THF, NaOH, H₂O₂ / tetrahydrofuran / Ambient temperature

6: 86 percent / t.BuOK / tetrahydrofuran / 65 °C

7: 96 percent / 10 percent aq. HCl / tetrahydrofuran / 18 h / Ambient temperature

8: Py, DMAP / Ambient temperature

With pyridine; hydrogenchloride; dmap; sodium hydroxide; sodium tetrahydroborate; borane-THF; oxalyl dichloride; potassium tert-butylate; dihydrogen peroxide; titanium tetrachloride; dimethyl sulfoxide; zinc; In tetrahydrofuran; ethanol; dichloromethane; tert-butyl alcohol;
DOI:10.1016/S0957-4166(00)82266-1

Reference yield:

: 50409-12-6,13314-30-2
cis,cis-1,3,5-trihydroxycyclohexane

: 130256-38-1
cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

Guidance literature:: Multi-step reaction with 9 steps

1: 84 percent / Amberlyst-15 / 1,2-dimethoxy-ethane / 2 h / 85 °C

2: 90 percent / NaBH₄ / ethanol / Ambient temperature

3: 73 percent / t.BuOK / 2-methyl-propan-2-ol / 65 °C

4: 96 percent / (COCl)2, DMSO / CH₂Cl₂ / -60 °C

5: 64 percent / Zn, TiCl₄ / tetrahydrofuran; CH₂Cl₂ / 0 °C

6: 88 percent / BH_3.THF, NaOH, H₂O₂ / tetrahydrofuran / Ambient temperature

7: 86 percent / t.BuOK / tetrahydrofuran / 65 °C

8: 96 percent / 10 percent aq. HCl / tetrahydrofuran / 18 h / Ambient temperature

9: Py, DMAP / Ambient temperature

With pyridine; hydrogenchloride; dmap; sodium hydroxide; sodium tetrahydroborate; amberlyst-15; borane-THF; oxalyl dichloride; potassium tert-butylate; dihydrogen peroxide; titanium tetrachloride; dimethyl sulfoxide; zinc; In tetrahydrofuran; 1,2-dimethoxyethane; ethanol; dichloromethane; tert-butyl alcohol;
DOI:10.1016/S0957-4166(00)82266-1

Reference yield:

: 130323-27-2
(1S,5R,7R)-3-Hydroxymethyl-2,4-dioxa-bicyclo[3.3.1]nonan-7-ol

: 130256-38-1
cis-5-benzyloxymethyl-1,3-diacetoxycyclohexane

Guidance literature:: Multi-step reaction with 7 steps

1: 73 percent / t.BuOK / 2-methyl-propan-2-ol / 65 °C

2: 96 percent / (COCl)2, DMSO / CH₂Cl₂ / -60 °C

3: 64 percent / Zn, TiCl₄ / tetrahydrofuran; CH₂Cl₂ / 0 °C

4: 88 percent / BH_3.THF, NaOH, H₂O₂ / tetrahydrofuran / Ambient temperature

5: 86 percent / t.BuOK / tetrahydrofuran / 65 °C

6: 96 percent / 10 percent aq. HCl / tetrahydrofuran / 18 h / Ambient temperature

7: Py, DMAP / Ambient temperature

With pyridine; hydrogenchloride; dmap; sodium hydroxide; borane-THF; oxalyl dichloride; potassium tert-butylate; dihydrogen peroxide; titanium tetrachloride; dimethyl sulfoxide; zinc; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;
DOI:10.1016/S0957-4166(00)82266-1