Ph₃GeSPh

Base Information

• Chemical Name: Ph₃GeSPh
• CAS No.: 2034-06-2
• Molecular Formula: C₂₄H₂₀GeS
• Molecular Weight: 413.079
• Mol file: 2034-06-2.mol

Synonyms:

Chemical Property of Ph₃GeSPh

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Ph₃GeSPh

There total 1 articles about Ph₃GeSPh which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

chlorotriphenylgermane (1626-24-0) + bis(benzenethiolato)lead(II) (32812-89-8) → Ph3GeSPh (2034-06-2)

Guidance literature:

In tetrahydrofuran; suspended Pb(SPh)2 and Ph3GeCl in THF, refluxed with stirring under inert gas;

Reference yield: 55.0%

tungsten hexacarbonyl (14040-11-0) + Ph3GeSPh (2034-06-2) → W(CO)5((C6H5)3GeS(C6H5)) (86774-17-6)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); under N2 atm. soln. W(CO)6 in THF irradiated with 100 W uv lamp for 4 h, soln. chilled rapidly to 0°C, Ph3GeSPh added, soln. stirred briefly, stored at -20°C in the dark overnight; soln. filtered, evapd. in vacuo at 40°C, residue extd. with hexane, extracts combined, concd., chromed. on Al2O3 with hexane, eluate evapd. to dryness, W(CO)6 sublimed at 40°C, residue recrystd. from hexane; elem. anal.;

Reference yield: 40.0%

[(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)] + Ph3GeSPh (2034-06-2) → [Os3(CO)8(μ-H)(μ-SPh)(μ-bis(diphenylphosphino)methane)] + [Os3(CO)7(μ-H)(μ-SPh)(μ-bis(diphenylphosphino)methane)(μ3-SC6H4)] (1144112-82-2,874988-83-7)

Guidance literature:

In benzene; (N2); using Schlenk techniques; reflux of benzene soln. of Os3(CO)8(μ-H)(μ3-Ph2PCH2P(Ph)C6H4) and Ph3GeSPh for 9 h; removal of solvent under reduced pressure; chromy. by TLC on silica gel;elution with hexane/CH2Cl2 (7:3, v/v); recrystn. from hexane/CH2Cl2 at 4°C; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.005

upstream raw materials:

chlorotriphenylgermane

bis(benzenethiolato)lead(II)

Downstream raw materials:

W(CO)5((C₆H₅)3GeS(C₆H₅))

[Os3(CO)7(μ-H)(μ-SPh)(μ-bis(diphenylphosphino)methane)(μ3-SC6H4)]