1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

Base Information

Chemical Name:1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane
CAS No.:73410-07-8
Molecular Formula:C₁₀H₁₈O
Molecular Weight:154.252
Hs Code.:

Synonyms:

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Chemical Property of 1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

Chemical Property:

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Technology Process of 1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

There total 10 articles about 1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1610839-55-8
C₁₂H₁₈O₄

: 73410-07-8
1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

Guidance literature:: With lithium borohydride; In tetrahydrofuran; isopropyl alcohol; at 0 ℃;
DOI:10.1016/j.tetasy.2014.01.019

Reference yield:

: 87802-43-5
4,4-dimethyl-5,5-(ethylenedioxy)-1-pentene

: 73410-07-8
1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

Guidance literature:: Multi-step reaction with 8 steps

1.1: diborane / tetrahydrofuran / 0 °C

1.2: 0 °C

2.1: triphenylphosphine; iodine; 1H-imidazole / dichloromethane / 2 h / 0 °C

3.1: toluene-4-sulfonic acid / water; acetone / 10 h / 50 °C

4.1: potassium carbonate / methanol / 12 h / 20 °C

5.1: sodium hydride / tetrahydrofuran / 0.08 h / 0 °C

5.2: 4 h / 0 - 50 °C

6.1: triethylamine; tin(IV) chloride / dichloromethane / 14 h / 20 °C

7.1: pig liver esterase; water / aq. phosphate buffer / 6 h / 30 °C / pH 8 / Enzymatic reaction

8.1: lithium borohydride / tetrahydrofuran; isopropyl alcohol / 0 °C

With 1H-imidazole; lithium borohydride; pig liver esterase; water; iodine; tin(IV) chloride; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; triphenylphosphine; diborane; In tetrahydrofuran; methanol; aq. phosphate buffer; dichloromethane; water; isopropyl alcohol; acetone;
DOI:10.1016/j.tetasy.2014.01.019

Reference yield:

: 104730-31-6
2-(4-hydroxy-1,1-dimethylbutyl)-1,3-dioxolane

: 73410-07-8
1-hydroxymethyl-2-methylene-3,3-dimethylcyclohexane

Guidance literature:: Multi-step reaction with 7 steps

1.1: triphenylphosphine; iodine; 1H-imidazole / dichloromethane / 2 h / 0 °C

2.1: toluene-4-sulfonic acid / water; acetone / 10 h / 50 °C

3.1: potassium carbonate / methanol / 12 h / 20 °C

4.1: sodium hydride / tetrahydrofuran / 0.08 h / 0 °C

4.2: 4 h / 0 - 50 °C

5.1: triethylamine; tin(IV) chloride / dichloromethane / 14 h / 20 °C

6.1: pig liver esterase; water / aq. phosphate buffer / 6 h / 30 °C / pH 8 / Enzymatic reaction

7.1: lithium borohydride / tetrahydrofuran; isopropyl alcohol / 0 °C

With 1H-imidazole; lithium borohydride; pig liver esterase; water; iodine; tin(IV) chloride; sodium hydride; potassium carbonate; toluene-4-sulfonic acid; triethylamine; triphenylphosphine; In tetrahydrofuran; methanol; aq. phosphate buffer; dichloromethane; water; isopropyl alcohol; acetone;
DOI:10.1016/j.tetasy.2014.01.019