VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2

Base Information

• Chemical Name: VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2
• CAS No.: 207295-83-8
• Molecular Formula: C₃₂H₅₀ClO₄V
• Molecular Weight: 585.141
• Mol file: 207295-83-8.mol

Synonyms:

Chemical Property of VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2

There total 1 articles about VCl(OC₆H₃-i-Pr₂-2,6)2(THF)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9) + lithium 2,6-diisopropylphenolate (72727-49-2) → VCl(OC6H3-i-Pr2-2,6)2(THF)2 (207295-83-8)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl, THF; inert atmosphere; stirring V-complex with 2 equiv. of phenoxide for 12 h; evapn., extn. into hexane, concn. (vac.), crystn. (-4°C), filtration, washing (hexane), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(97)00774-2

Reference yield: 50.0%

Li-2,4,6-trimethylbenzenethiolate (111975-80-5) + VCl(OC6H3-i-Pr2-2,6)2(THF)2 (207295-83-8) → V(SC6H2Me3-2,4,6)(OC6H3-i-Pr2-2,6)2(THF)2

Guidance literature:

In tetrahydrofuran; inert atmosphere; stirring equimolar amts. for 5 h; evapn., extn. into hexane, concn. (vac.), crystn. (-4°C), filtration, washing (hexane), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(97)00774-2

Reference yield:

VCl(OC6H3-i-Pr2-2,6)2(THF)2 (207295-83-8) + tetrakis(trimethylsilyl)hydrazine (20156-62-1) → VO(OC6H3-i-Pr2-2,6)3 (207295-84-9)

Guidance literature:

In hexane; byproducts: N2; inert atmosphere; stirring equimolar amts. for 24 h; solvent removal (vac.), heating (60°C, vac.), extn. into hexane, crystn. (-4°C, several d), filtration; elem. anal.;

DOI:10.1016/S0022-328X(97)00774-2

upstream raw materials:

Vanadium (III) chloride-(tris-tetrahydrofuran)

lithium 2,6-diisopropylphenolate

Downstream raw materials:

VO(OC₆H₃-i-Pr₂-2,6)3