methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

Base Information

Chemical Name:methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate
CAS No.:151985-49-8
Molecular Formula:C₂₇H₄₀O₃Si
Molecular Weight:440.698
Hs Code.:

Synonyms:

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Chemical Property of methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

Chemical Property:

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Technology Process of methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

There total 14 articles about methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 112-47-0
1,10-Decanediol

: 151985-49-8
methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

Guidance literature:: Multi-step reaction with 14 steps

1: 40 percent / sodium hydride / tetrahydrofuran; dimethylformamide / 1.) 0 deg C, 1 h, 2.) room temperature, 12 h

2: 68 percent / Jones reagent

3: 98 percent

4: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

5: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

6: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

7: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

8: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

9: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

10: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

11: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

12: 79 percent / hydrogen / 10percent palladium carbon

13: 69 percent / pyridinium dichromate, molecular sieves 3A / CH₂Cl₂

14: 1.) 30percent H₂O₂, sodium dihydrogenphosphate, sodium chloride / 1.) H₂O, acetonitrile, 0 deg C, 2 h

With 1H-imidazole; titanium(IV) isopropylate; sodium dihydrogenphosphate; lithium aluminium tetrahydride; dipyridinium dichromate; jones reagent; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; hydrogen; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; sodium chloride; lithium diisopropyl amide; palladium carbon; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 144482-51-9
methyl 10-benzyloxydecanoate

: 151985-49-8
methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

Guidance literature:: Multi-step reaction with 11 steps

1: 46 percent / lithium diisopropylamide / tetrahydrofuran; hexane / 0.5 h / -78 °C

2: 74 percent / 30percent H₂O₂, sodium hydrocarbonate / tetrahydrofuran / 1.) 0 deg C, 2.) room temperature, 1 h

3: 93 percent / diisobutylaluminum hydride / CH₂Cl₂; toluene / 0.5 h / -78 °C

4: 74 percent / tetra-iso-propyl titanate, L-(+)-diethyl tartrate, molecular sieves 3A / CH₂Cl₂ / 3 h / -25 °C

5: 40 percent / sodium bis(2-methoxyethoxy)aluminum hydride, (+)-diisopropyl tartrate / tetrahydrofuran; toluene / 1.) 0 deg C, 2 h, 2.) room temperature, 72 h

6: 59 percent / sodium hydride / dimethylformamide / 1 h / 0 °C

7: 61 percent / lithium aluminum hydride / tetrahydrofuran / 4 h / 0 °C

8: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

9: 79 percent / hydrogen / 10percent palladium carbon

10: 69 percent / pyridinium dichromate, molecular sieves 3A / CH₂Cl₂

11: 1.) 30percent H₂O₂, sodium dihydrogenphosphate, sodium chloride / 1.) H₂O, acetonitrile, 0 deg C, 2 h

With 1H-imidazole; titanium(IV) isopropylate; sodium dihydrogenphosphate; lithium aluminium tetrahydride; dipyridinium dichromate; L-(+)-diisopropyl tartrate; diethyl (2R,3R)-tartrate; 3 A molecular sieve; hydrogen; dihydrogen peroxide; sodium hydride; diisobutylaluminium hydride; sodium hydrogencarbonate; sodium bis(2-methoxyethoxy)aluminium dihydride; sodium chloride; lithium diisopropyl amide; palladium carbon; In tetrahydrofuran; hexane; dichloromethane; N,N-dimethyl-formamide; toluene;

Reference yield:

: 151985-45-4
(3R)-10-benzyloxy-3-decanol

: 151985-49-8
methyl (8R)-8-tert-butyldiphenylsilyloxydecanoate

Guidance literature:: Multi-step reaction with 4 steps

1: 51 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

2: 79 percent / hydrogen / 10percent palladium carbon

3: 69 percent / pyridinium dichromate, molecular sieves 3A / CH₂Cl₂

4: 1.) 30percent H₂O₂, sodium dihydrogenphosphate, sodium chloride / 1.) H₂O, acetonitrile, 0 deg C, 2 h

With 1H-imidazole; sodium dihydrogenphosphate; dipyridinium dichromate; 3 A molecular sieve; hydrogen; dihydrogen peroxide; sodium chloride; palladium carbon; In dichloromethane; N,N-dimethyl-formamide;