[Cp2(OC)4Mo2(μPPhEt)(μ-H)]

Base Information

• Chemical Name: [Cp2(OC)4Mo2(μPPhEt)(μ-H)]
• CAS No.: 347385-00-6
• Molecular Formula: C₂₂H₂₁Mo₂O₄P
• Molecular Weight: 572.26
• Mol file: 347385-00-6.mol

Synonyms:

Chemical Property of [Cp2(OC)4Mo2(μPPhEt)(μ-H)]

Chemical Property:

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Technology Process of [Cp2(OC)4Mo2(μPPhEt)(μ-H)]

There total 1 articles about [Cp2(OC)4Mo2(μPPhEt)(μ-H)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

tetrafluoroboric acid diethyletherate + cis/trans-[Cp2(OC)4Mo2(μ-η1:η2-P(Ph)=C(H)Me)] (258278-91-0,258278-96-5) + L-Selectride → [Cp2(OC)4Mo2(μPPhEt)(μ-H)] (347385-00-6)

Guidance literature:

In tetrahydrofuran; under N2 atm. soln. LiB(sBu)3H in THF was added dropwise at -78°Cto soln. cis/trans-(Cp2(OC)4Mo2(μ-η1:η2-P(Ph)=C(H)Me)) in TH F and stirred for 30 min, HBF4*Et2O was added; solvent was removed under vac., residue was dissolved in CH2Cl2 and filtered; elem. anal.;

DOI:10.1021/om001089k

upstream raw materials:

cis/trans-[Cp2(OC)4Mo2(μ-η1:η2-P(Ph)=C(H)Me)]