CH₃Rh(C₂₀H₈N₄(C₆H₄CH₃)4)NCC₅H₄N

Base Information

• Chemical Name: CH₃Rh(C₂₀H₈N₄(C₆H₄CH₃)4)NCC₅H₄N
• CAS No.: 301526-49-8
• Molecular Formula: C₅₅H₄₃N₆Rh
• Molecular Weight: 890.892
• Mol file: 301526-49-8.mol

Synonyms:

Chemical Property of CH₃Rh(C₂₀H₈N₄(C₆H₄CH₃)4)NCC₅H₄N

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of CH₃Rh(C₂₀H₈N₄(C₆H₄CH₃)4)NCC₅H₄N

There total 2 articles about CH₃Rh(C₂₀H₈N₄(C₆H₄CH₃)4)NCC₅H₄N which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

pyridine-4-carbonitrile (100-48-1) + (5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III) (103533-61-5) → CH3Rh(C20H8N4(C6H4CH3)4)NCC5H4N (301526-49-8)

Guidance literature:

In dichloromethane; addn. of excess of ligand to a soln. of rhodium complex in CH2Cl2, stirring at room temp. for 30 min; concn., addn. of hexane, cooling to -10°C, washing with cold methanol;

DOI:10.1016/S0022-328X(01)01097-X

Reference yield:

pyridine-4-carbonitrile (100-48-1) + (5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III) (103533-61-5) → Rh(TTP)(CH3)(CNpy) (301526-49-8)

Guidance literature:

In dichloromethane; stirred, room temperature, 30 min, excess of PyCN; hexane additn., crystn. (CH2Cl2-hexane, room temperature);

DOI:10.1016/S0022-328X(00)00236-9

upstream raw materials:

pyridine-4-carbonitrile

(5,10,15,20-tetrakis-4-tolylporphyrinato)(methyl)rhodium(III)