cinnamyl tosylate

Base Information

• Chemical Name: cinnamyl tosylate
• CAS No.: 78480-08-7
• Molecular Formula: C₁₆H₁₆O₃S
• Molecular Weight: 288.367
• Mol file: 78480-08-7.mol

Synonyms:

Chemical Property of cinnamyl tosylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cinnamyl tosylate

There total 2 articles about cinnamyl tosylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

p-toluenesulfonyl chloride (98-59-9) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → cinnamyl tosylate (19627-30-6,78480-08-7,91861-44-8)

Guidance literature:

With aluminum dodecatungstophosphate; at 20 ℃; for 0.233333h;

DOI:10.1139/V06-066

Reference yield: 90.0%

toluene-4-sulfonic acid (104-15-4) + (2E)-3-phenyl-2-propen-1-ol (4407-36-7) → cinnamyl tosylate (19627-30-6,78480-08-7,91861-44-8)

Guidance literature:

cobalt(II) chloride; In 1,2-dichloro-ethane; for 0.5h; Heating;

DOI:10.1016/j.tetlet.2003.10.106

Reference yield: 94.0%

cinnamyl tosylate (19627-30-6,78480-08-7,91861-44-8) + ammonium thiocyanate (1147550-11-5) → (E)-(3-thiocyanatoprop-1-en-1-yl)benzene (74394-96-0,149666-39-7)

Guidance literature:

ammonium thiocyanate; With montmorillonite K₁₀ clay; In acetone; at 20 ℃; for 0.666667h;

cinnamyl tosylate; at 20 ℃; for 0.05h; Neat (no solvent); Grinding;

DOI:10.1016/j.tetlet.2012.01.113

upstream raw materials:

p-toluenesulfonyl chloride

(2E)-3-phenyl-2-propen-1-ol

toluene-4-sulfonic acid

Downstream raw materials:

erythro-N,N-dimethyl-2-methyl-3-phenylthiopent-4-enamide

threo-N,N-dimethyl-2-methyl-3-phenylthiopent-4-enamide

erythro-N,N-dimethyl-2,3-diphenylthiopent-4-enamide

threo-N,N-dimethyl-2-phenyl-3-methylthiopent-4-enamide