Technology Process of Zn(N4C20H8(C6H3(C(CH3)3)2)3C6H4C2HN3C6H4CHO)
There total 5 articles about Zn(N4C20H8(C6H3(C(CH3)3)2)3C6H4C2HN3C6H4CHO) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium ascorbate;
copper(l) iodide;
In
water; dimethyl sulfoxide;
other Radiation; (Ar) alkynylporphyrin, azidobenzaldehyde, CuI and sodium ascorbate in DMSO-H2O (9:1) were heated in CEM Discover LabMate microwave reactor at 50W for 30 min; product was extd. with CH2Cl2 and chromd. on silica (CH2Cl2);
DOI:10.1021/ja202485s
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2,3-dicyano-5,6-dichloro-p-benzoquinone
2: zinc(II) acetate dihydrate / methanol / 1 h / Reflux
3: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 20 °C
4: copper(l) iodide; sodium L-ascorbate / water; dimethyl sulfoxide / 80 °C / Inert atmosphere; Microwave irradiation
With
copper(l) iodide; tetrabutyl ammonium fluoride; zinc(II) acetate dihydrate; sodium L-ascorbate; 2,3-dicyano-5,6-dichloro-p-benzoquinone;
In
tetrahydrofuran; methanol; water; dimethyl sulfoxide;
4: Huisgen cycloaddition;
DOI:10.1021/ja202485s
- Guidance literature:
-
Multi-step reaction with 3 steps
1: zinc(II) acetate dihydrate / methanol / 1 h / Reflux
2: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 20 °C
3: copper(l) iodide; sodium L-ascorbate / water; dimethyl sulfoxide / 80 °C / Inert atmosphere; Microwave irradiation
With
copper(l) iodide; tetrabutyl ammonium fluoride; zinc(II) acetate dihydrate; sodium L-ascorbate;
In
tetrahydrofuran; methanol; water; dimethyl sulfoxide;
3: Huisgen cycloaddition;
DOI:10.1021/ja202485s
