CH₃Bi(SC₆H₄NH₂)2

Base Information

• Chemical Name: CH₃Bi(SC₆H₄NH₂)2
• CAS No.: 115029-38-4
• Molecular Formula: C₁₃H₁₅BiN₂S₂
• Molecular Weight: 472.388
• Mol file: 115029-38-4.mol

Synonyms:

Chemical Property of CH₃Bi(SC₆H₄NH₂)2

Chemical Property:

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Technology Process of CH₃Bi(SC₆H₄NH₂)2

There total 1 articles about CH₃Bi(SC₆H₄NH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.1%

methyldibromobismuth(III) (60458-17-5) + Li(1+)*H2NC6H4S(1-) = LiSC6H4NH2 → CH3Bi(SC6H4NH2)2 (115029-38-4)

Guidance literature:

In diethyl ether; benzene; byproducts: LiBr; slow addn. of suspn. of CH3BiBr2 in diethyl ether to suspn. of LiSC6H4NH2-p in benzene under stirring, ratio of Bi compd. to LiSC6H4NH2-p = 1:2, 14h, 25°C, evapn. in vac. to dryness, extn. with CH3OH; in inert atm.; dry, argon saturated solvents; washed with CS2 and ether, dried in vac.; elem. anal.;

DOI:10.1016/0022-328X(87)80002-5

Reference yield: 97.9%

CH3Bi(SC6H4NH2)2 (115029-38-4) → {CH3Bi(SC6H4NH2CH3)2}(2+)*2I(1-)={CH3Bi(SC6H4NH2CH3)2}I2

Guidance literature:

With methyl iodide; In acetone; addn. of CH3I to soln. of Bi compd., 3h, reflux, 2h stirred at 25°C, evapn. in vac. to dryness, 48h dried in vac.; in inert atm.; dry, argon saturated solvents; elem. anal.;

DOI:10.1016/0022-328X(87)80002-5

upstream raw materials:

methyldibromobismuth(III)