Re(P(p-C₆H₄F)3)2H₇

Base Information

• Chemical Name: Re(P(p-C₆H₄F)3)2H₇
• CAS No.: 82948-74-1
• Molecular Formula: C₃₆H₃₁F₆P₂Re
• Molecular Weight: 825.787

Synonyms:

Chemical Property of Re(P(p-C₆H₄F)3)2H₇

Chemical Property:

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Technology Process of Re(P(p-C₆H₄F)3)2H₇

There total 1 articles about Re(P(p-C₆H₄F)3)2H₇ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ReOCl3(P(p-C6H4F)3)2 (108009-10-5) → Re(P(p-C6H4F)3)2H7 (82948-74-1)

Guidance literature:

With lithium aluminium hydride; In diethyl ether; ReOCl3(P(p-C6H4F)3)2 was was placed under vac. for 1 h, ether was vac.transferred into the flask, LiAlH4 was added over 10 min, kept for 30 min; filtered, filtrate was evapd., excess LiAlH4 was decompd. by wet CH2Cl2 (-40°C) and H2O (0°C) under N2, mixt. was filtered, cooled by addn. of liq. N2, decanted, evapd. (10**-3 Torr), residue was washed with Et2O under N2, dried under vac.;

Reference yield:

Re(P(p-C6H4F)3)2H7 (82948-74-1) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → CpRe(P(p-C6H4F)3)2H2

Guidance literature:

In tetrahydrofuran; THF soln. of the Re-complex was treated with 100 equiv of cyclopentadiene under inert atmosphere followed by gentle heating; elem. anal.;

Reference yield:

Re(P(p-C6H4F)3)2H7 (82948-74-1) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → C41H31F6P2Re

Guidance literature:

In not given; react. biphosphine rhenium heptahydride with cyclopentadiene as in D.Baudry, M.Ephritikhine J.Chem.Soc.,Chem.Commun, 1980, 249; D.Baudry, M.Ephritikhine, H.Felkin, J.Organomet.Chem., 1982, 244, 363;

DOI:10.1039/c39820000606

upstream raw materials:

ReOCl₃(P(p-C₆H₄F)3)2

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