(η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2

Base Information

Chemical Name:(η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2
CAS No.:1296275-63-2
Molecular Formula:C₃₄H₃₄Cl₂Ti
Molecular Weight:561.43
Hs Code.:

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Chemical Property of (η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2

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Technology Process of (η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2

There total 1 articles about (η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: titanium(IV) chloride tetrahydrofuran

: 1296275-71-2
1,2,3,5-Me₄-4-(PhCC)C₅H

: 1296275-63-2
(η5-(1,2,3,5-Me4-4-(PhCC)C5))2TiCl2

Guidance literature:: With (n)BuLi; In tetrahydrofuran; hexane; under Ar; to soln. of ligand (20.15 mmol) in hexane was added (n)BuLi (20.04 mmol) in hexane at 0°C; warming to room temp., stirring overnight; suspn. was filtered, evapd. to dryness; addn. of THF and Ti-contg. compd. (10.02 mmol) (-78°C); after stirring at room temp. overnight, solvent was removed at reduced pressure, residue was extd. with CH2Cl2 and soln. was filtered through Celite; solvent was removed in vac., compd. was recrystd. from a mixt. of Et2O and hexane; elem. anal.;
DOI:10.1016/j.poly.2011.02.011