N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide

Base Information

• Chemical Name: N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide
• CAS No.: 1207738-94-0
• Molecular Formula: C₂₈H₂₉FeN₂*I
• Molecular Weight: 576.303
• Mol file: 1207738-94-0.mol

Synonyms:

Chemical Property of N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide

There total 1 articles about N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

1‐(2,4,6‐trimethylbenzyl)benzimidazole + N,N,N-(ferrocenylmethyl)trimethylammonium iodide → N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide (1207738-94-0)

Guidance literature:

In acetonitrile; (Ar), Fe complex slowly added to soln. of 1.1 equiv. of ligand in CH3CN,refluxed for 48 h; evapd.(vac.), chromy.(silica gel - CH2Cl2/acetone 8:2), elem. anal.;

DOI:10.1002/ejic.200801163

Reference yield: 86.0%

methoxy(cyclooctadiene)rhodium(I) dimer + N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazolium iodide (1207738-94-0) → [N-(ferrocenylmethyl)-N'-[(2,4,6-trimethylphenyl)methyl]benzimidazol-2-ylidene](cyclootadiene)rhodium(I) iodide

Guidance literature:

In dichloromethane; (Ar), mixt. of Fe anf Rh complexes (2:1) in Ch2Cl2 stirred at room temp.for 6 h; concd., pptd.(pentane), filtered, chromy.(silica gel - CH2Cl2), elem. anal.;

DOI:10.1002/ejic.200801163