2,2-di-tert-butyloxirane

Base Information

• Chemical Name: 2,2-di-tert-butyloxirane
• CAS No.: 41979-14-0
• Molecular Formula: C₁₀H₂₀O
• Molecular Weight: 156.268
• Mol file: 41979-14-0.mol

Synonyms:Butane,2-tert-butyl-1,2-epoxy-3,3-dimethyl- (6CI); 2,2-Di-tert-butyloxirane; NSC311949

Chemical Property of 2,2-di-tert-butyloxirane

Chemical Property:

• Vapor Pressure: 3.87mmHg at 25°C
• Boiling Point: 155.6°C at 760 mmHg
• Flash Point: 45.6°C
• Density: 0.891g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,2-di-tert-butyloxirane

There total 3 articles about 2,2-di-tert-butyloxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

di-t-butyl-1,1 ethylene (5857-68-1) → 2,2-di-tert-butyloxirane (41979-14-0)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 2h; Ambient temperature;

DOI:10.1016/0040-4020(84)85013-9

Reference yield:

2,2-di-tert-butyl-3-chlorooxirane → 2,2-di-tert-butyloxirane (41979-14-0) + 2-tert-butyl-3,3-dimethylbutanal (2987-13-5)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 51h; UV-irradiation;

DOI:10.1002/ejoc.201000888

Reference yield:

→ 2,2-di-tert-butyloxirane (41979-14-0)

Guidance literature:

DOI:10.1021/ja01495a025 DOI:10.1021/ja00791a084

upstream raw materials:

di-t-butyl-1,1 ethylene

Refernces

• 1、 Kimpe, Norbert De,Buyck, Laurent De,Verhe, Roland,Schamp, Niceas. "A UNIQUE AND HIGHLY REMARKABLE BORON TRIFLUORIDE CATALYZED REARRANGEMENT OF 2,2-DI-t-BUTYLOXIRANE INTO 2,2,3,3,4,4-HEXAMETHYLTETRAHYDROFURAN". . p. 3291 - 3294. Retrieved 2007/10/02.