(-)-(C₅Me₅)Fe(C₉H₉O)

Base Information

Chemical Name:(-)-(C₅Me₅)Fe(C₉H₉O)
CAS No.:1291105-28-6
Molecular Formula:C₄₄H₃₄FeO
Molecular Weight:634.6
Hs Code.:

(-)-(C<sub>5</sub>Me<sub>5</sub>)Fe(C<sub>9</sub>H<sub>9</sub>O)

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Chemical Property of (-)-(C₅Me₅)Fe(C₉H₉O)

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Technology Process of (-)-(C₅Me₅)Fe(C₉H₉O)

There total 2 articles about (-)-(C₅Me₅)Fe(C₉H₉O) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1291105-27-5
[(C₅(C₆H₅)5)Fe(C₅H₄CH₂CH₂CH₂COOH)]

: 1291105-28-6,1291105-32-2,1291105-33-3
(+/-)-(C₅Ph₅)Fe(C₉H₉O)

Guidance literature:: With trifluoroacetic anhydride; In tetrachloromethane; using Schlenk techniquus; charging of (C5Ph5)Fe(C5H4(CH2)3COOH) and CCl4to flask, wrapping with Al foil, bubbling with Ar for 10 min, cooling t o 0°C, addn. of (CF3CO)2O via syringe, stirring at 50°C overnight; transferring into funnel, sepn. between 10% NaOH and CH2Cl2, washing of org. phase with brine, drying over Na2SO4, filtration, removal of volatiles under reduced pressure, flash chromy. (SiO2, hexanes/CH2Cl2/Et2O 20/20/1);
DOI:10.1021/om2002206

Reference yield: 78.0%

: 1291105-28-6,1291105-32-2,1291105-33-3
(+/-)-(C₅Ph₅)Fe(C₉H₉O)

: 33993-53-2
N,S-dimethyl-S-phenylsulfoximine

: 1291105-28-6,1291105-32-2,1291105-33-3
(-)-(C₅Me₅)Fe(C₉H₉O)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; (N2); using Schlenk techniques; addn. of n-BuLi in hexane to soln. of (+)-OS(CH3)(C6H5)NCH3 in THF at 0°C, stirring for 15 min at this temp., cooling to -78°C, addn. of (C5Ph5)Fe(C9H9O) for 10 min, stirring for 3 h, warming to -20°C; addn. of NH4Cl, diluting (H2O), extn. (ether), washing (brine), drying (Na2SO4), concn. to dryness under reduced pressure at room temp., chromy.(SiO2, hexanes/CH2Cl2/EtOAc 20/10/1), dissolving in MePh, reflux overni ght;
DOI:10.1021/om2002206

Reference yield: 78.0%

: 1291105-28-6,1291105-32-2,1291105-33-3
(+/-)-(C₅Ph₅)Fe(C₉H₉O)

: 33993-53-2
N,S-dimethyl-S-phenylsulfoximine

: 1291105-28-6,1291105-32-2,1291105-33-3
(-)-(C₅Me₅)Fe(C₉H₉O)

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; (N2); using Schlenk techniques; addn. of n-BuLi in hexane to soln. of (+)-OS(CH3)(C6H5)NCH3 in THF at 0°C, stirring for 15 min at this temp., cooling to -78°C, addn. of (C5Ph5)Fe(C9H9O) for 10 min, stirring for 3 h, warming to -20°C; addn. of NH4Cl, diluting (H2O), extn. (ether), washing (brine), drying (Na2SO4), concn. to dryness under reduced pressure at room temp., chromy.(SiO2, hexanes/CH2Cl2/EtOAc 20/10/1), dissolving in MePh, reflux overni ght;
DOI:10.1021/om2002206