(OC)5ReRe(CO)4P(C₆H₅)3

Base Information

Chemical Name:(OC)5ReRe(CO)4P(C₆H₅)3
CAS No.:27770-63-4
Molecular Formula:C₂₇H₁₅O₉PRe₂
Molecular Weight:886.798
Hs Code.:

(OC)5ReRe(CO)4P(C<sub>6</sub>H<sub>5</sub>)3

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (OC)5ReRe(CO)4P(C₆H₅)3

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Technology Process of (OC)5ReRe(CO)4P(C₆H₅)3

There total 5 articles about (OC)5ReRe(CO)4P(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 33634-75-2
sodium pentacarbonylrhenate

: 70083-75-9
pentacarbonyl(triphenylphosphane)rhenium tetrafluoroborate

: 27770-63-4,51371-62-1,64599-46-8
(OC)5ReRe(CO)4P(C₆H₅)3

Guidance literature:: In tetrahydrofuran; byproducts: (OC)5Re-Re(CO)5, NaBF4, CO; under N2, suspn. of Re-complex in THF, addn. of soln. NaRe(CO)5 in THF under stirring at -78 ° C, stirring at room temp. for 20 min; sepn. of NaBF4, evapn. of THF, residue stirred for 10 min at -78 °C in methanol, sepn. of colorless residue from yellow soln., dried in high vac., sublimation at 50 °C; elem. anal.;
DOI:10.1016/0022-328X(89)87258-4

Reference yield: 45.3%

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 27770-63-4,51371-62-1,64599-46-8
Re₂(CO)9(P(C₆H₅)3)

: 27770-64-5,88082-39-7,14172-94-2,119677-58-6
Re₂(CO)8(PPh₃)2

: Re(CO)3P(C₆H₅)3(C₆H₄P(C₆H₅)2)

: 19032-55-4,25734-54-7,64599-47-9
fac-HRe(CO)3(PPh₃)2

: 25734-54-7
trans-mer-Re(H)(PPh₃)2(CO)3

Guidance literature:: With triphenylphosphine; In xylene; (N2); Re complex and PPh3 (0.57:4.77 mol) were refluxed in xylene for 48 h, then solvent was removed in vac.; further products; residue was dissolved in boiling benzene and hexane added at 60°C, on ice-cooling pptd. powder was recrystd. from benzene/hexane; elem. anal.; filtrate was concd., yielding Re(CO)3(PPh3)(C6H4PPh2) by crystn. from ether; further products from TLC;
DOI:10.1016/S0022-328X(00)82414-6

Reference yield: 33.7%

: 14285-68-8
decacarbonyldirhenium⁽⁰⁾

: 27770-63-4,51371-62-1,64599-46-8
(OC)5ReRe(CO)4P(C₆H₅)3

Guidance literature:: With triphenylphosphine; In xylene; (N2); soln. of Re complex and PPh3 (1:1 mol) was refluxed for 19 h; solvent was removed in vac., residue sepd. by preparative TLC (silicagel, PE/ethyl acetate 3/1); elem. anal.;
DOI:10.1016/S0022-328X(00)82414-6