trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II)

Base Information

• Chemical Name: trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II)
• CAS No.: 171021-87-7
• Molecular Formula: C₄₄H₅₆Cl₂N₂O₄P₂Ru
• Molecular Weight: 910.863
• Mol file: 171021-87-7.mol

Synonyms:

Chemical Property of trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II)

There total 1 articles about trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

trans-dichloro-cis-bis{diphenyl(1,3-dioxan-2-ylmethyl)phosphane-O,P}ruthenium(II) (140658-04-4) + tert-butylisonitrile (119072-55-8,7188-38-7) → trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II) (171021-87-7)

Guidance literature:

In toluene; Ar-atmosphere; slight excess of t-BuNC, refluxing for 1 h; pptn. on cooling, collection; elem. anal.;

DOI:10.1021/ic00128a023

Reference yield: 63.0%

trans-dichloro-cis-bis{diphenyl(1,3-dioxan-2-ylmethyl)phosphane-O,P}ruthenium(II) (140658-04-4) + trans-bis(tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P]ruthenium(II) (171021-87-7) → (tert-butyl isocyanide)-cis-dichloro-cis-bis[(1,3-dioxan-2-ylmethyl)diphenylphosphine-P;O',P']ruthenium(II)

Guidance literature:

In toluene; Ar-atmosphere; equimolar amts., refluxing for 1 h; crystn. on cooling to room temp., collection, washing (pentane), drying(vac.); elem. anal.;

DOI:10.1021/ic00128a023

upstream raw materials:

trans-dichloro-cis-bis{diphenyl(1,3-dioxan-2-ylmethyl)phosphane-O,P}ruthenium(II)

tert-butylisonitrile