1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene

Base Information

• Chemical Name: 1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene
• CAS No.: 225782-13-8
• Molecular Formula: C₅₂H₁₄Cl₂₈Fe
• Molecular Weight: 1687.21
• Mol file: 225782-13-8.mol

Synonyms:

Chemical Property of 1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene

There total 1 articles about 1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1'-ferrocenyldicarboxaldehyde (1271-48-3) + α,α-bis(pentachlorophenyl)-2,3,5,6-tetrachloro-α'-(triphenylphosphonium)-p-xylene bromide → 1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene (225782-13-8,401941-72-8)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; treatment of phosphonium bromide with 1 equiv. KOtBu, stirring suspension for 1 h, addn. of aldehyde, stirring (72 h), quenching (HCl); extn. (CHCl3), chromy. (hexane-CHCl3);

DOI:10.1039/a900371a

Reference yield:

1,1'-bis[4-[bis(pentachlorophenyl)methyl]-2,3,5,6-tetrachlorostyryl]ferrocene (225782-13-8,401941-72-8) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → 4,4'-(1,1'ferrocenylenedivinylene)-di[α,α-bis(pentachlorophenyl)-2,3,5,6-tetrachlorobenzyl] radical*2C6H6

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; chloranil; In tetrahydrofuran; treatment of ferrocene with Bu4NOH, stirring (room temp., 4 h), treatment with chloranil; chromy. (n-hexane-CCl4), recrystn. (C6H6); elem. anal., IR, UV-VIS;

DOI:10.1039/a900371a

upstream raw materials:

1,1'-ferrocenyldicarboxaldehyde

Refernces