4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate

Base Information

Chemical Name:4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate
CAS No.:150512-87-1
Molecular Formula:C₁₆H₁₅BrN₂O₄
Molecular Weight:379.21
Hs Code.:
DSSTox Substance ID:DTXSID801144275
Nikkaji Number:J2.284.814C

Synonyms:SCHEMBL8909201;DTXSID801144275;150512-87-1

Suppliers and Price of 4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate

Chemical Property:

XLogP3:2.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:6
Exact Mass:378.02152
Heavy Atom Count:23
Complexity:434

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC(=CC(=N1)C2=CC(=CC(=N2)CBr)C(=O)OC)C(=O)OC

Technology Process of 4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate

There total 3 articles about 4,4'-Dimethyl 6-(bromomethyl)-6'-methyl[2,2'-bipyridine]-4,4'-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 345604-52-6
6,6'-dimethyl-4,4'-dicarbomethoxy-2,2'-bipyridine mono-N-oxide

: 150512-87-1
dimethyl 6-(bromomethyl)-6'-methyl-2,2'-bipyridine-4,4'-dicarboxylate

Guidance literature:: 6,6'-dimethyl-4,4'-dicarbomethoxy-2,2'-bipyridine mono-N-oxide; With trifluoroacetic anhydride;

With lithium bromide; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(01)00306-9

Reference yield:

: 117330-40-2
dimethyl 6,6'-dimethyl-2,2'-bipyridine-4,4'-dicarboxylate

: 150512-87-1
dimethyl 6-(bromomethyl)-6'-methyl-2,2'-bipyridine-4,4'-dicarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: m-chloroperbenzoic acid / CH₂Cl₂ / 2.5 h / 20 °C

2.1: trifluoroacetic anhydride / CH₂Cl₂ / 1.5 h / Heating

2.2: 55 percent / LiBr / dimethylformamide; tetrahydrofuran / 4 h

With 3-chloro-benzenecarboperoxoic acid; trifluoroacetic anhydride; In dichloromethane;
DOI:10.1002/ejic.200300690