(E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

Base Information

Chemical Name:(E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene
CAS No.:162375-20-4
Molecular Formula:C₂₄H₄₄SiSn
Molecular Weight:479.409
Hs Code.:

Synonyms:

Suppliers and Price of (E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

There total 1 articles about (E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 31683-47-3
1-(trimethylsilyl)-3-phenylprop-1-yne

: 926-62-5
isobutylmagnesium bromide

: 1461-22-9
tributyltin chloride

: 162375-20-4,796056-00-3
(E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

Guidance literature:: bis(cyclopentadienyl)titanium dichloride; In diethyl ether; byproducts: MgBrCl; under Ar; Ti complex (5 mol%) added to soln. of i-BuMgBr in Et2O at 0°C; stirred at 0°C for 30 min; alkynylsilane added; stirred at 25°C for 6 h; cooled to 0°C; soln. of n-Bu3SnCl in Et2O added; stirred at room temp. for 4 h; quenched with satd. aq. NH4Cl; extd. with Et2O; org. layer washed with satd. aq. NH4Cl and H2O; dried over MgSO4; filtrate evapd. under vac.; column chromy. (silica gel, light petroleum ether); elem. anal.;
DOI:10.1016/j.jorganchem.2004.07.063

Reference yield: 75.0%

: 591-50-4
iodobenzene

: 162375-20-4,796056-00-3
(E)-1-trimethylsilyl-1-tributylstannyl-3-phenyl-1-propene

: (Z)-1-trimethylsilyl-1,3-diphenyl-1-propene

Guidance literature:: With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 20 ℃; for 48h;
DOI:10.1016/j.jorganchem.2004.07.063