bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate

Base Information

• Chemical Name: bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate
• CAS No.: 129596-71-0
• Molecular Formula: C₅₄H₅₂AuP₄*F₆P
• Molecular Weight: 1166.83
• Mol file: 129596-71-0.mol

Synonyms:

Chemical Property of bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate

There total 1 articles about bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

ammonium hexafluorophosphate + chloroauric acid + 1,3-bis-(diphenylphosphino)propane (6737-42-4) → bis{1,2-bis(diphenylphosphino)propane}gold(I) hexafluorophosphate (129596-71-0)

Guidance literature:

With 2,2'-thiodiethanol; In water; acetone; addn. of thiodiethanol in acetone to HAuCl4 in H2O, cooling to 0°C, addn. of phosphine ligand in acetone, stirring for 20 min, slow warming to 45°C, stirring for 20 min, cooling to room temp., filtn., addn. of NH4PF6 in H2O; addn. of H2O, standing overnight at 4°C, filtn. of a gummy solid, washing with acetone-H2O and then with ether, redissolution of dried solid in acetone, addn. of ether, filtn.;

DOI:10.1039/DT9900002219

upstream raw materials:

1,3-bis-(diphenylphosphino)propane