6-Trityloxy-4-methylhex-4-ensaeure

Base Information

• Chemical Name: 6-Trityloxy-4-methylhex-4-ensaeure
• CAS No.: 33431-27-5
• Molecular Formula: C₂₆H₂₆O₃
• Molecular Weight: 386.491
• Mol file: 33431-27-5.mol

Synonyms:

Chemical Property of 6-Trityloxy-4-methylhex-4-ensaeure

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-Trityloxy-4-methylhex-4-ensaeure

There total 5 articles about 6-Trityloxy-4-methylhex-4-ensaeure which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

6-Trityloxy-4-methylhex-4-enal (33431-26-4) → 6-Trityloxy-4-methylhex-4-ensaeure (33431-27-5)

Guidance literature:

With potassium hydroxide; silver nitrate; In 1,4-dioxane;

DOI:10.1016/S0040-4020(01)88962-6

Reference yield:

(E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enyl acetate (37715-31-4) → 6-Trityloxy-4-methylhex-4-ensaeure (33431-27-5)

Guidance literature:

Multi-step reaction with 3 steps

1: aq. HClO₄ / bis-(2-methoxy-ethyl) ether

2: (i) aq. NaOH, MeOH, (ii) aq. NaIO₄, (iii) /BRN= 397363/, Py

3: AgNO₃, aq. KOH / dioxane

With potassium hydroxide; perchloric acid; silver nitrate; In 1,4-dioxane; diethylene glycol dimethyl ether;

DOI:10.1016/S0040-4020(01)88962-6

Reference yield:

(2E)-6,7-epoxy-3,7-dimethyl-1-triphenylmethoxy-2-octene (92464-72-7) → 6-Trityloxy-4-methylhex-4-ensaeure (33431-27-5)

Guidance literature:

Multi-step reaction with 3 steps

1: aq. HClO₄ / bis-(2-methoxy-ethyl) ether

2: aq. NaIO₄ / tetrahydrofuran

3: AgNO₃, aq. KOH / dioxane

With potassium hydroxide; sodium periodate; perchloric acid; silver nitrate; In tetrahydrofuran; 1,4-dioxane; diethylene glycol dimethyl ether;

DOI:10.1016/S0040-4020(01)88962-6

upstream raw materials:

6-Trityloxy-4-methylhex-4-enal

(E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enyl acetate

(2E)-6,7-epoxy-3,7-dimethyl-1-triphenylmethoxy-2-octene

1-Trityloxy-6,7-dihydroxy-3,7-dimethyloct-2-en

Downstream raw materials:

methyl (E)-6-hydroxy-4-methylhex-4-enoate