carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

Base Information

Chemical Name:carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium
CAS No.:91424-01-0
Molecular Formula:C₁₈H₂₂AsORh
Molecular Weight:432.199
Hs Code.:

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Chemical Property of carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

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Technology Process of carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

There total 2 articles about carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: (η(5)-pentamethylcyclopentadienyl)Rh(CH2I)(CO)I

: 822-65-1
phenylarsane

: 91424-01-0
carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

Guidance literature:: With n-C₄H₉Li; In diethyl ether; hexane; byproducts: LiI; (Ar); ether soln. of PhAsH2 was treated with BuLi in hexane, to mixt. was added Rh complex in THF, stirred for 3 h at 25°C and evapd. to dryness; residue was extd. with pentane, evapd., hexane soln. of residue was chromd. (Al2O3, hexane); orange-yellow fraction evapd., residue crystd. from pentane at -78°C, washed with pentane and dried in vac.; elem. anal.;

Reference yield: 37.0%

: (η(5)-pentamethylcyclopentadienyl)Rh(CH2I)(CO)I

: 1073-41-2,40965-94-4
Lithium-phenylarsan

: 91424-01-0
carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

Guidance literature:: In tetrahydrofuran; diethyl ether; byproducts: LiI, C6H5AsH2; adding a soln. of the Rh complex in THF to a Et2O soln. of LiAsHPh (prepd. from PhAsH2 and nBuLi), stirring (3 h, room temp.); evapg., chromy. (Al2O3, benzene/pentane), recrystn. (pentane, 25 - -78°C);

Reference yield: 20.0%

: 91424-01-0
carbonyl(η2-methylenephenylarsane)(η5-pentamethylcyclopentadienyl)rhodium

: 91410-81-0
carbonyl(η5-pentamethylcyclopentadienyl)(1,2,3-triphenyl-1,3-triarsanediyl)rhodium

Guidance literature:: In pentane; (Ar); satd. soln. of Rh complex was kept at -78°C for 8 - 10 d; from formed yellow powder were sepd. orange crystals after decanting solvent and drying in vac.; elem. anal.;