[(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4

Base Information

• Chemical Name: [(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4
• CAS No.: 88510-48-9
• Molecular Formula: C₂₄H₂₀B*C₄₂H₄₃NNiP₃
• Molecular Weight: 1032.66
• Mol file: 88510-48-9.mol

Synonyms:

Chemical Property of [(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4

There total 2 articles about [(((C₆H₅)2PCH₂CH₂)3N)NiH]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(((C₆H₅)2PCH₂CH₂)3N)NiH]B(C₆H₅)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

(N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)(1+)*B(C6H5)4(1-)=[(N(CH2CH2P(C6H5)2)3)Ni(CO2C2H5)]B(C6H5)4 (95099-93-7) → [(((C6H5)2PCH2CH2)3NH)Ni(CO)](1+)*B(C6H5)4(1-)=[(((C6H5)2PCH2CH2)3NH)Ni(CO)]B(C6H5)4 (88440-33-9) + [(((C6H5)2PCH2CH2)3N)NiH](1+)*B(C6H5)4(1-)=[(((C6H5)2PCH2CH2)3N)NiH]B(C6H5)4 (88510-48-9)

Guidance literature:

With borane-THF; In tetrahydrofuran; soln. of BH3*THF added to complex soln., refluxed for 5 h; BuOH added, evapd., filtered;

DOI:10.1016/0022-328X(84)80663-4

Reference yield:

(tris(2-diphenylphosphinoethyl)amine)nickel(0) (52633-73-5,97135-31-4) + sodium tetraphenyl borate (143-66-8) → [(((C6H5)2PCH2CH2)3N)NiH](1+)*B(C6H5)4(1-)=[(((C6H5)2PCH2CH2)3N)NiH]B(C6H5)4 (88510-48-9)

Guidance literature:

With acetic acid; In tetrahydrofuran; byproducts: CH3COONa; 3 equiv of acetic acid was added to soln. of 2 equiv of Ni-complex in THF at room temp., 2 equiv of NaBPh4 in EtOH was added; concd. under stream of N2, filtered, washed with EtOH and petroleum ether; elem. anal.;

Reference yield:

[(((C6H5)2PCH2CH2)3N)NiH](1+)*B(C6H5)4(1-)=[(((C6H5)2PCH2CH2)3N)NiH]B(C6H5)4 (88510-48-9) → (NH(CH2CH2P(C6H5)2)3)NiCO(1+)*B(C6H5)4(1-)*0.5C4H8O=((NH(CH2CH2P(C6H5)2)3)NiCO)B(C6H5)4*0.5C4H8O (88510-49-0)

Guidance literature:

With carbon monoxide; In solid; solid Ni-complex was placed under CO at room temp. and atm. pressure, stream of CO was passed for ca. 10 d; evacuated, filled with dry N2, dissolved in THF, filtered, EtOH added, concd. under stream of N2, filtered, washed with EtOH and petroleum ether; elem. anal.;

upstream raw materials:

(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)⁽¹⁺⁾*B(C₆H₅)4^(1-)=[(N(CH₂CH₂P(C₆H₅)2)3)Ni(CO₂C₂H₅)]B(C₆H₅)4

(tris(2-diphenylphosphinoethyl)amine)nickel⁽⁰⁾

sodium tetraphenyl borate

Downstream raw materials:

(NH(CH₂CH₂P(C₆H₅)2)3)NiCO⁽¹⁺⁾*B(C₆H₅)4^(1-)*0.5C₄H₈O=((NH(CH₂CH₂P(C₆H₅)2)3)NiCO)B(C₆H₅)4*0.5C₄H₈O

[(tris(2-(diphenylphosphino)ethyl)amine)NiCO]BPh₄