methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Base Information

Chemical Name:methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate
CAS No.:138840-70-7
Molecular Formula:C₂₆H₃₃O₁₁P
Molecular Weight:552.515
Hs Code.:

methyl <allyl 5-O-<bis(benzyloxy)phosphinoyl>-3-deoxy-β-D-manno-2-octulopyranosid>onate

Synonyms:

Suppliers and Price of methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

There total 8 articles about methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 114826-98-1
methyl (3aR,4R,7aR)-4-[(R)-2,2-dimethyl-1,3-dioxolan-4-yl]-6-hydroxy-2,2-dimethyltetrahydro-3aH-[1,3]dioxolo[4,5-c]pyran-6-carboxylate

: 138840-70-7
methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Guidance literature:: Multi-step reaction with 6 steps

1: pyridine, 4-dimethylaminopyridine / CH₂Cl₂ / 1 h / Ambient temperature

2: 66 percent / 70percent HF-pyridine / CH₂Cl₂ / 1.) -20 deg C, 10 min, 2.) 0 deg C, 10 min

3: 24 percent / N,N-diisopropylethylamine, BF₃ etherate / CH₂Cl₂ / 0.08 h / 0 °C

4: 99 percent / 95percent aq. trifluoroacetic acid (TFA) / CH₂Cl₂ / 1 h / 0 °C

5: 64 percent / (+)-camphorsulfonic acid (CSA) / tetrahydrofuran / 2 h / Ambient temperature

With pyridine; dmap; boron trifluoride diethyl etherate; pyridine hydrogenfluoride; (+)-10-camphorsulfonic acid; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.64.3267

Reference yield:

: methyl 3-deoxy-D-manno-2-octulosonate

: 138840-70-7
methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Guidance literature:: Multi-step reaction with 7 steps

1: p-toluenesulfonic acid monohydrate / 13 h / Ambient temperature

2: pyridine, 4-dimethylaminopyridine / CH₂Cl₂ / 1 h / Ambient temperature

3: 66 percent / 70percent HF-pyridine / CH₂Cl₂ / 1.) -20 deg C, 10 min, 2.) 0 deg C, 10 min

4: 24 percent / N,N-diisopropylethylamine, BF₃ etherate / CH₂Cl₂ / 0.08 h / 0 °C

5: 99 percent / 95percent aq. trifluoroacetic acid (TFA) / CH₂Cl₂ / 1 h / 0 °C

6: 64 percent / (+)-camphorsulfonic acid (CSA) / tetrahydrofuran / 2 h / Ambient temperature

With pyridine; dmap; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; pyridine hydrogenfluoride; (+)-10-camphorsulfonic acid; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.64.3267

Reference yield:

: 114826-99-2
methyl (3-deoxy-4,5;7,8-di-O-isopropylidene-α-D-mannooct-2-ulopyranosyl)onate fluoride

: 138840-70-7
methyl -3-deoxy-β-D-manno-2-octulopyranosid>onate

Guidance literature:: Multi-step reaction with 4 steps

1: 24 percent / N,N-diisopropylethylamine, BF₃ etherate / CH₂Cl₂ / 0.08 h / 0 °C

2: 99 percent / 95percent aq. trifluoroacetic acid (TFA) / CH₂Cl₂ / 1 h / 0 °C

3: 64 percent / (+)-camphorsulfonic acid (CSA) / tetrahydrofuran / 2 h / Ambient temperature

With boron trifluoride diethyl etherate; (+)-10-camphorsulfonic acid; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1246/bcsj.64.3267