[(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2O

Base Information

• Chemical Name: [(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2O
• CAS No.: 1280103-59-4
• Molecular Formula: C₅₈H₈₆Ge₂N₄O
• Molecular Weight: 1000.53
• Mol file: 1280103-59-4.mol

Synonyms:

Chemical Property of [(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2O

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2O

There total 3 articles about [(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

trimethylamine-N-oxide (1184-78-7) + [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl] (915151-35-8) → [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2 (915151-36-9) + [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O (1280103-59-4)

Guidance literature:

With KC₈; In tetrahydrofuran; (Ar); using Schlenk techniques; addn. of THF to mixt. of (t-Bu)C(NC6H3(CH(CH3)2)2)2GeCl (2 equiv.), Me3NO and KC8 (2 equiv.) at -78°C, stirring at room temp. for 12 h; removal of volatiles by vac., extn. with Et2O, filtration, concn., crystn. at room temp. for 1 day; elem. anal.;

DOI:10.1021/om101194f

Reference yield:

[(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2 (915151-36-9) + trimethylamine-N-oxide (1184-78-7) → [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O (1280103-59-4)

Guidance literature:

In tetrahydrofuran; (Ar); using Schlenk techniques; treatment of (Ge(t-Bu)C(N(2,6-(i-Pr)2C6H3))2)2 with 1 equiv. of Me3NO in THF; monitoring by NMR;

DOI:10.1021/om101194f

Reference yield:

sodium oxide + [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2GeCl] (915151-35-8) → [(t-Bu)C(N(2,6-(i-Pr)2C6H3))2Ge]2O (1280103-59-4)

Guidance literature:

In tetrahydrofuran; (Ar); using Schlenk techniques; treatment of (t-Bu)C(NC6H3(CH(CH3)2)2)2GeCl with Na2O in THF;

DOI:10.1021/om101194f

upstream raw materials:

trimethylamine-N-oxide

[(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2GeCl]

[(t-Bu)C(N(2,6-(i-Pr)2C₆H₃))2Ge]2