2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

Base Information

Chemical Name:2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione
CAS No.:344403-89-0
Molecular Formula:C₄₄H₄₃NO₇Si
Molecular Weight:725.913
Hs Code.:

2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

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Suppliers and Price of 2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

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Chemical Property of 2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

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Technology Process of 2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

There total 5 articles about 2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 10022-13-6
1,3,4,6-tetra-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranose

: 344403-89-0
2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

Guidance literature:: Multi-step reaction with 5 steps

1: NH₂NH₂; AcOH / dimethylformamide

2: imidazole; 4-dimethylaminopyridine / dimethylformamide

3: t-BuOK / methanol; tetrahydrofuran

4: camphorsulfonic acid / acetonitrile

5: NaH / dimethylformamide

With 1H-imidazole; dmap; camphor-10-sulfonic acid; potassium tert-butylate; sodium hydride; acetic acid; hydrazine; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(01)00342-2

Reference yield:

: 72858-55-0
3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 344403-89-0
2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

Guidance literature:: Multi-step reaction with 4 steps

1: imidazole; 4-dimethylaminopyridine / dimethylformamide

2: t-BuOK / methanol; tetrahydrofuran

3: camphorsulfonic acid / acetonitrile

4: NaH / dimethylformamide

With 1H-imidazole; dmap; camphor-10-sulfonic acid; potassium tert-butylate; sodium hydride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(01)00342-2

Reference yield:

: 344403-87-8
2-[(2S,3R,4R,5S,6R)-2-(tert-Butyl-diphenyl-silanyloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-3-yl]-isoindole-1,3-dione

: 344403-89-0
2-[(2R,4aR,6S,7R,8R,8aS)-8-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl]-isoindole-1,3-dione

Guidance literature:: Multi-step reaction with 2 steps

1: camphorsulfonic acid / acetonitrile

2: NaH / dimethylformamide

With camphor-10-sulfonic acid; sodium hydride; In N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4039(01)00342-2