bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I)

Base Information

• Chemical Name: bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I)
• CAS No.: 153735-03-6
• Molecular Formula: C₇H₈Cl₂Rh*C₃₆H₃₀NP₂
• Molecular Weight: 804.54
• Mol file: 153735-03-6.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I)

There total 4 articles about bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cis-bis(triphenylphosphine)iminium dichlorodicarbonylrhodium(I) (89654-69-3) + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I) (153735-03-6)

Guidance literature:

In further solvent(s); addn. of diolefin to a filtd. soln. of Rh-complex in 2-methoxyethanol under N2, refluxing for 3 h, colour changes from pale yellow to yelloworange; removal of solvent under reduced pressure, collection of residue, washing with Et2O, drying in vacuo at 50°C, recrystn. from CH2Cl2/Et2O, elem. anal.;

Reference yield:

bis(triphenylphosphine)iminium dichloro(1,5-cyclooctadiene)rhodium(I) (153735-02-5) → bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I) (153735-03-6)

Guidance literature:

Multi-step reaction with 2 steps

1: CO / not given

2: further solvent(s)

With CO; In not given; further solvent(s);

Reference yield:

cis-bis(triphenylphosphine)iminium dichlorodicarbonylrhodium(I) (89654-69-3) → bis(triphenylphosphine)iminium dichloro(norbornadiene)rhodium(I) (153735-03-6)

Guidance literature:

Multi-step reaction with 3 steps

1: further solvent(s)

2: CO / not given

3: further solvent(s)

With CO; In further solvent(s); not given;

upstream raw materials:

[(norbornadiene)rhodium(I)chloride]2

bis(triphenylphosphine)iminium chloride

cis-bis(triphenylphosphine)iminium dichlorodicarbonylrhodium(I)

bicyclo[2.2.1]hepta-2,5-diene

Downstream raw materials:

cis-bis(triphenylphosphine)iminium dichlorodicarbonylrhodium(I)

bis(triphenylphosphine)iminium dichloro(1,5-cyclooctadiene)rhodium(I)